Classification of structurally related compounds from Astragalus extract by correlation of the logk(w) and S
文献类型：期刊论文
| 作者 | Xiao, HB; Liang, XM; Lu, PC |
| 刊名 | chromatographia
 |
| 出版日期 | 2000-02-01 |
| 卷号 | 51期号:3-4页码:212-220 |
| 关键词 | column liquid chromatography classification of structurally related compounds correlation of the logk(w) and S complex unknown sample Astragalus extract |
| 英文摘要 | the linear relationship between logk(w) and s derived from molecular interactions and statistical thermodynamics was investigated by four series of different polar probe solutes. for each series of similar polar solutes, structurally related compounds with similar dipolarity/polarizability and hydrogen bonding energy, a linear relationship between logk(w) and s was obtained. the more similar the solutes, the greater were the regression coefficients obtained. for two series of solutes with different strong polar groups resulting in different dipolarity/polarizability and hydrogen bonding energy, two parallel lines were observed in the logk(w)-s plots. each line represented one series of compounds and the distance between them indicated the difference in the dipolarity/polarizability and hydrogen bonding energy. based on the parallel lines implying information on structurally related compounds in the logk(w)-s plot, a method of classification of structurally related compounds was put forward and the linear logk(w)-s correlation for unknown components in nonaqueous rp-hplc analysis of astragalus extract with isopropanol-methanol mobile phase was studied. two nearly parallel lines were obtained in the logk(w)-s plot and two series of structurally related compounds were classified in this way. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; physical sciences |
| 类目[WOS] | biochemical research methods ; chemistry, analytical |
| 研究领域[WOS] | biochemistry & molecular biology ; chemistry |
| 关键词[WOS] | performance liquid-chromatography ; retention behavior ; molecular-structure ; organic modifiers ; gradient elution ; mobile-phase ; equation ; index |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000085855100014 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138720]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, HB,Liang, XM,Lu, PC. Classification of structurally related compounds from Astragalus extract by correlation of the logk(w) and S[J]. chromatographia,2000,51(3-4):212-220. |
| APA | Xiao, HB,Liang, XM,&Lu, PC.(2000).Classification of structurally related compounds from Astragalus extract by correlation of the logk(w) and S.chromatographia,51(3-4),212-220. |
| MLA | Xiao, HB,et al."Classification of structurally related compounds from Astragalus extract by correlation of the logk(w) and S".chromatographia 51.3-4(2000):212-220. |
入库方式： OAI收割
来源：大连化学物理研究所
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