Heat capacity and thermodynamic properties of (1R,2S,5R)-2-i-propyI-5-methylcyclohexyl diazoacetate
文献类型:期刊论文
作者 | Di, YY; Tan, ZC; Li, ZN; Song, YJ; Zheng, Y; Meng, SH; Qu, SS |
刊名 | thermochimica acta
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出版日期 | 2000-11-13 |
卷号 | 362期号:1-2页码:7-12 |
关键词 | (1R heat capacity adiabatic calorimeter chemical purity 2S 5R)-2-i-propyi-5-methylcyclohexyl diazoacetate |
英文摘要 | heat capacities of (1r,2s,5r)-2-i-propyl-5-methylcyclohexyl diazoacetate have been measured with a small sample adiabatic calorimeter over the temperature range from 78 to 344 k. the melting point, molar enthalpy and entropy of fusion as well as the chemical purity of this compound were determined to be 320.419 +/- 0.017 k, 17.203 +/- 0.005 kj mol(-1),53.689 +/- 0.013jk(-1) mol(-1) and 99.61 mol%, respectively, on the basis of the heat-capacity measurements. the extrapolated melting temperature for the absolutely pure compound obtained from fractional melting experiments was 320.602 k. (c) 2000 elsevier science b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, analytical ; chemistry, physical |
研究领域[WOS] | chemistry |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000165324700002 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/138731] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China 2.Wuhan Univ, Coll Chem & Environm Sci, Wuhan 430072, Peoples R China |
推荐引用方式 GB/T 7714 | Di, YY,Tan, ZC,Li, ZN,et al. Heat capacity and thermodynamic properties of (1R,2S,5R)-2-i-propyI-5-methylcyclohexyl diazoacetate[J]. thermochimica acta,2000,362(1-2):7-12. |
APA | Di, YY.,Tan, ZC.,Li, ZN.,Song, YJ.,Zheng, Y.,...&Qu, SS.(2000).Heat capacity and thermodynamic properties of (1R,2S,5R)-2-i-propyI-5-methylcyclohexyl diazoacetate.thermochimica acta,362(1-2),7-12. |
MLA | Di, YY,et al."Heat capacity and thermodynamic properties of (1R,2S,5R)-2-i-propyI-5-methylcyclohexyl diazoacetate".thermochimica acta 362.1-2(2000):7-12. |
入库方式: OAI收割
来源:大连化学物理研究所
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