Effect of functional monomer on chiral separation ability of molecular imprinted chiral stationary phase
文献类型：期刊论文
| 作者 | Wang, JF; Zhou, LM; Liu, XL; Wang, QH; Zhu, DQ |
| 刊名 | acta chimica sinica
 |
| 出版日期 | 2000 |
| 卷号 | 58期号:3页码:351-355 |
| 关键词 | molecule imprinted polymer basic functional monomer combined functional monomers chiral stationary phase amino acid derivatives |
| 英文摘要 | the effect of functional monomer on chiral separation ability of the non - covalent molecular imprinted chiral stationary phase was investigated systematically. it was found that there was compatibleness between the functional monomer and the template molecules. strong hydrogen bond and ionic interaction could be formed between the amide group and carboxyl group in the amino acid derivatives and acrylamide and 2 vinylpyridine, which made the imprinting effect of the combined functional monomers am + 2 - vp more evident. the competing solvent acetic acid showed great influence on the non - covalent interaction between the analyte and the functional groups of molecular imprinted polymer (mip). ionic interaction and hydrogen bending between amide group and carboxyl group in the analyte and the functional groups of mip were weakened by increasing the concentration of the competing solvent acetic acid, therefore both the capacity factor, chiral selectivity faster and resolution decreased. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | polymers ; recognition ; resolution |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000087090300019 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138744]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, JF,Zhou, LM,Liu, XL,et al. Effect of functional monomer on chiral separation ability of molecular imprinted chiral stationary phase[J]. acta chimica sinica,2000,58(3):351-355. |
| APA | Wang, JF,Zhou, LM,Liu, XL,Wang, QH,&Zhu, DQ.(2000).Effect of functional monomer on chiral separation ability of molecular imprinted chiral stationary phase.acta chimica sinica,58(3),351-355. |
| MLA | Wang, JF,et al."Effect of functional monomer on chiral separation ability of molecular imprinted chiral stationary phase".acta chimica sinica 58.3(2000):351-355. |
入库方式： OAI收割
来源：大连化学物理研究所
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