Gas chromatographic enantiomer separation of mandelates and its analogs on permethylated cyclodextrin chiral stationary phases
文献类型：期刊论文
| 作者 | Nie, MY; Zhou, LM; Wang, QH; Zhu, DQ |
| 刊名 | chinese journal of analytical chemistry
 |
| 出版日期 | 2000-11-01 |
| 卷号 | 28期号:11页码:1366-1370 |
| 关键词 | enantiomer separation cyclodextrin derivatives alpha-hydroxycarboxylic acids enthalpyentropy compensation |
| 英文摘要 | gas chromatographic enantionmer separation of mandelates and its analogs was investigated on permethylated beta -cyclodextrin (pmbcd) and permethylated gamma -cyclodextrin (pmgcd) chiral stationary phases(csps). the compounds investigated included methyl and ethyl mandelates, methyl and ethyl alpha -methoxymandelates, methyl and ethyl 3-phenylacetates, ethyl 2-hydroxy-4-phenyl butyrate. au the compounds studied can be chirally separated to baseline an pmbcd csps, hut no enantiomer separation was observed on pmgcd csps for all the tested compounds, some thermodynamic data were evaluated and used to delve the mechanism of chiral recognition between permethylated cyclodextrins and mandelates and their analogs. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | enthalpy-entropy compensation ; beta-cyclodextrin ; resolution |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000165648000010 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138764]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Nie, MY,Zhou, LM,Wang, QH,et al. Gas chromatographic enantiomer separation of mandelates and its analogs on permethylated cyclodextrin chiral stationary phases[J]. chinese journal of analytical chemistry,2000,28(11):1366-1370. |
| APA | Nie, MY,Zhou, LM,Wang, QH,&Zhu, DQ.(2000).Gas chromatographic enantiomer separation of mandelates and its analogs on permethylated cyclodextrin chiral stationary phases.chinese journal of analytical chemistry,28(11),1366-1370. |
| MLA | Nie, MY,et al."Gas chromatographic enantiomer separation of mandelates and its analogs on permethylated cyclodextrin chiral stationary phases".chinese journal of analytical chemistry 28.11(2000):1366-1370. |
入库方式： OAI收割
来源：大连化学物理研究所
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