Thermodynamic study on separation of molecular imprinting chiral stationary phase
文献类型：期刊论文
| 作者 | Wang, JF; Zhou, LM; Liu, XL; Wang, QH; Zhu, DQ |
| 刊名 | chemical journal of chinese universities-chinese
 |
| 出版日期 | 2000-06-01 |
| 卷号 | 21期号:6页码:930-933 |
| 关键词 | molecular imprinting polymer chiral stationary phase chiral separation mechanism thermodynamic parameter |
| 英文摘要 | the effect of temperature on the chiral separation of the molecular imprinting polymer was investigated and the thermodynamic parameters were calculated, it was found that the chiral separation process was enthalpy-controlled. increasing the temperature decreases the capacity factor and chiral selectivity factor. the interactions between the analyte and the molecular imprinting chiral stationary phase were both non-specific and specific, and only the difference of specific interaction results in the chiral separation. the imprinting cavities affected the thermodynamic parameters dramatically, the rebinding of the imprinted molecule into the imprinting cavities was favorable in view of energy and configuration because of their best compatibleness. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | functional monomers ; polymers ; recognition ; resolution |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000087772500026 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138774]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, JF,Zhou, LM,Liu, XL,et al. Thermodynamic study on separation of molecular imprinting chiral stationary phase[J]. chemical journal of chinese universities-chinese,2000,21(6):930-933. |
| APA | Wang, JF,Zhou, LM,Liu, XL,Wang, QH,&Zhu, DQ.(2000).Thermodynamic study on separation of molecular imprinting chiral stationary phase.chemical journal of chinese universities-chinese,21(6),930-933. |
| MLA | Wang, JF,et al."Thermodynamic study on separation of molecular imprinting chiral stationary phase".chemical journal of chinese universities-chinese 21.6(2000):930-933. |
入库方式： OAI收割
来源：大连化学物理研究所
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