Multiphoton ionization and ab initio calculation of C4H5N-(NH3)n hydrogen-bond clusters
文献类型:期刊论文
作者 | Li, Y; Hu, YJ; Lu, RC; Wang, XY |
刊名 | acta physico-chimica sinica
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出版日期 | 2000-09-01 |
卷号 | 16期号:9页码:810-817 |
关键词 | multiphoton ionization pyrrole TOF-MS binary cluster |
英文摘要 | multiphoton ionization of binary clusters (c4h5n) -nh3 at 355 and 532 nm have been investigated using a tof mass spectrometer, the experimenal results showed that normal cluster ions and protonated cluster ions were produced at both laser wavelengths. the protonated products came from the intracluster proton transfer reaction. the existence of nh3 in the clusters increased the ionization cross sections of the clusters, the higher ionization efficiency at 355 nm results from the (2 + 1) resonance multiphoton ionization of the pyrrole molecule. a peculiar low abundance of (c4h5n)- (nh3)(2)(+) was observed, ab initio calculations indicated that when ammonia number n greater than or equal to 3, two hydrogen bonds between ammnia chain and pyrrole ring can be formed, and the cluster become more stable. the channel ratio for the formation of protonated and unprotonated products increases with the increase of n, in agreement with the trend of proton affinity of (c4h5n) - (nh3)(n), |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | pyrrole-water |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000089651200010 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/138809] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Y,Hu, YJ,Lu, RC,et al. Multiphoton ionization and ab initio calculation of C4H5N-(NH3)n hydrogen-bond clusters[J]. acta physico-chimica sinica,2000,16(9):810-817. |
APA | Li, Y,Hu, YJ,Lu, RC,&Wang, XY.(2000).Multiphoton ionization and ab initio calculation of C4H5N-(NH3)n hydrogen-bond clusters.acta physico-chimica sinica,16(9),810-817. |
MLA | Li, Y,et al."Multiphoton ionization and ab initio calculation of C4H5N-(NH3)n hydrogen-bond clusters".acta physico-chimica sinica 16.9(2000):810-817. |
入库方式: OAI收割
来源:大连化学物理研究所
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