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Chinese Academy of Sciences Institutional Repositories Grid
Multiphoton ionization and ab initio calculation of C4H5N-(NH3)n hydrogen-bond clusters

文献类型:期刊论文

作者Li, Y; Hu, YJ; Lu, RC; Wang, XY
刊名acta physico-chimica sinica
出版日期2000-09-01
卷号16期号:9页码:810-817
关键词multiphoton ionization pyrrole TOF-MS binary cluster
英文摘要multiphoton ionization of binary clusters (c4h5n) -nh3 at 355 and 532 nm have been investigated using a tof mass spectrometer, the experimenal results showed that normal cluster ions and protonated cluster ions were produced at both laser wavelengths. the protonated products came from the intracluster proton transfer reaction. the existence of nh3 in the clusters increased the ionization cross sections of the clusters, the higher ionization efficiency at 355 nm results from the (2 + 1) resonance multiphoton ionization of the pyrrole molecule. a peculiar low abundance of (c4h5n)- (nh3)(2)(+) was observed, ab initio calculations indicated that when ammonia number n greater than or equal to 3, two hydrogen bonds between ammnia chain and pyrrole ring can be formed, and the cluster become more stable. the channel ratio for the formation of protonated and unprotonated products increases with the increase of n, in agreement with the trend of proton affinity of (c4h5n) - (nh3)(n),
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]pyrrole-water
收录类别SCI
语种英语
WOS记录号WOS:000089651200010
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/138809]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Li, Y,Hu, YJ,Lu, RC,et al. Multiphoton ionization and ab initio calculation of C4H5N-(NH3)n hydrogen-bond clusters[J]. acta physico-chimica sinica,2000,16(9):810-817.
APA Li, Y,Hu, YJ,Lu, RC,&Wang, XY.(2000).Multiphoton ionization and ab initio calculation of C4H5N-(NH3)n hydrogen-bond clusters.acta physico-chimica sinica,16(9),810-817.
MLA Li, Y,et al."Multiphoton ionization and ab initio calculation of C4H5N-(NH3)n hydrogen-bond clusters".acta physico-chimica sinica 16.9(2000):810-817.

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来源:大连化学物理研究所

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