Separation of the enantiomers of 2-phenylcyclopropanecarboxylate esters by capillary gas chromatography on derivatized cyclodextrin stationary phases
文献类型：期刊论文
| 作者 | Nie, MY; Zhou, LM; Liu, XL; Wang, QH; Zhu, DQ |
| 刊名 | chromatographia
 |
| 出版日期 | 2000-04-01 |
| 卷号 | 51期号:7-8页码:450-454 |
| 关键词 | gas chromatography chiral separation cyclodextrin derivatives enthalpy-entropy compensation iso-enthalpy behavior |
| 英文摘要 | separation of the enantiomers of 2-phenylcyclopropanecarboxylate esters has been investigated on derivatized cyclodextrin chiral stationary phases (cd csps) to enable direct determination of the enantiomeric purity of the products of enantioselective cyclopropanation. four stereoisomers of these chiral compounds could be resolved to baseline on permethylated p-cyclodextrin csp. some unusual phenomena, iso-enthalpy retention behavior and entropically driven chiral separation, were observed for the enantioseparation of 2-phenylcyclopropanecarboxylates on the cd csps. thermodynamic parameters were evaluated and an enthalpy-entropy compensation effect was observed for n-alkyl esters of 2-phenylcyclopropanecarboxylate separated on cd csps. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; physical sciences |
| 类目[WOS] | biochemical research methods ; chemistry, analytical |
| 研究领域[WOS] | biochemistry & molecular biology ; chemistry |
| 关键词[WOS] | enthalpy-entropy compensation ; performance liquid-chromatography ; enantioselective cyclopropanation ; acid enantiomers ; ligands ; olefins ; complexes |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000086898300012 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138811]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Nie, MY,Zhou, LM,Liu, XL,et al. Separation of the enantiomers of 2-phenylcyclopropanecarboxylate esters by capillary gas chromatography on derivatized cyclodextrin stationary phases[J]. chromatographia,2000,51(7-8):450-454. |
| APA | Nie, MY,Zhou, LM,Liu, XL,Wang, QH,&Zhu, DQ.(2000).Separation of the enantiomers of 2-phenylcyclopropanecarboxylate esters by capillary gas chromatography on derivatized cyclodextrin stationary phases.chromatographia,51(7-8),450-454. |
| MLA | Nie, MY,et al."Separation of the enantiomers of 2-phenylcyclopropanecarboxylate esters by capillary gas chromatography on derivatized cyclodextrin stationary phases".chromatographia 51.7-8(2000):450-454. |
入库方式： OAI收割
来源：大连化学物理研究所
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