Selective hydrogenation of ethyne on gamma-Mo2N
文献类型:期刊论文
作者 | Hao, ZX; Wei, ZB; Wang, LJ; Li, XH; Li, C; Min, EZ; Xin, Q |
刊名 | applied catalysis a-general
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出版日期 | 2000-02-07 |
卷号 | 192期号:1页码:81-84 |
关键词 | gamma-Mo2N ethyne ethene selective hydrogenation |
英文摘要 | the hydrogenation of ethyne on a gamma-mo2n catalyst has been investigated at 50-210 degrees c. with reaction time increasing, the selectivity of ethene in the products rose up gradually at 150 degrees c. a conversion of ca. 85% ethyne and selectivity of ca. 85% for ethene were obtained at 130 degrees c after the reaction became steady. selectivity remained almost unchanged with the varying of reaction temperature and space velocity. these results can be explained by bond's model, and firmly held adspecies (fha) and/or coke species from ethyne may be responsible for the high selectivity of ethene. (c) 2000 elsevier science b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
类目[WOS] | chemistry, physical ; environmental sciences |
研究领域[WOS] | chemistry ; environmental sciences & ecology |
关键词[WOS] | ethylene hydrogenation ; co ; molybdenum ; carbides ; acetylene ; catalysts ; mechanism ; nitrides ; tungsten |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000084664600009 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/138813] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Res Inst Petr Proc, Beijing 100083, Peoples R China |
推荐引用方式 GB/T 7714 | Hao, ZX,Wei, ZB,Wang, LJ,et al. Selective hydrogenation of ethyne on gamma-Mo2N[J]. applied catalysis a-general,2000,192(1):81-84. |
APA | Hao, ZX.,Wei, ZB.,Wang, LJ.,Li, XH.,Li, C.,...&Xin, Q.(2000).Selective hydrogenation of ethyne on gamma-Mo2N.applied catalysis a-general,192(1),81-84. |
MLA | Hao, ZX,et al."Selective hydrogenation of ethyne on gamma-Mo2N".applied catalysis a-general 192.1(2000):81-84. |
入库方式: OAI收割
来源:大连化学物理研究所
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