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Chinese Academy of Sciences Institutional Repositories Grid
Mass spectrometric study of Ag's clustering ability with O, S and Se

文献类型:期刊论文

作者Xing, XP; Zhang, X; Zhao, X; Gao, Z
刊名chinese science bulletin
出版日期2001-04-01
卷号46期号:7页码:543-549
关键词laser ablation time-of-flight mass spectrometer Ag/O(S clustering ability Se) atom clusters
英文摘要samples ag/o/s, ag/o/se and ag/s/se were ablated directly by laser to produce clusters. the detection was performed with a time-of-flight mass spectrometer (tof ms). the cluster ions produced had the following distribution: ag/s binary cluster ions for sample ag/o/s, ag/se binary cluster ions for sample ag/o/se, and ag/se binary cluster ions and ag/s/se ternary cluster ions as the main products for sample ag/s/se. laser double ablation reactor was used to study the reaction between ag/s(se, o) binary clusters and se(s) homoclusters. the experiments show that se clusters can replate s and o in ag/s and ag/o clusters while s clusters can replace o in ag/o clusters. this fact indicates the sequence of the clustering ability of ag presented as follows: ag/se > ak/s > ag/o, which was also proved by theoretical calculation. the reason of thsi tendency was considered to be the different abilities of the elements' polarization, which acts on the stability of clusters.
WOS标题词science & technology
类目[WOS]multidisciplinary sciences
研究领域[WOS]science & technology - other topics
关键词[WOS]electronic-structure ; sulfur ; ions ; photodissociation ; geometry ; silver
收录类别SCI
语种英语
WOS记录号WOS:000168549700003
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/138867]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Acad Sinica, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
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GB/T 7714
Xing, XP,Zhang, X,Zhao, X,et al. Mass spectrometric study of Ag's clustering ability with O, S and Se[J]. chinese science bulletin,2001,46(7):543-549.
APA Xing, XP,Zhang, X,Zhao, X,&Gao, Z.(2001).Mass spectrometric study of Ag's clustering ability with O, S and Se.chinese science bulletin,46(7),543-549.
MLA Xing, XP,et al."Mass spectrometric study of Ag's clustering ability with O, S and Se".chinese science bulletin 46.7(2001):543-549.

入库方式: OAI收割

来源:大连化学物理研究所

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