Low-temperature heat capacity and thermochemical study of [Re-2(Pro)(6)(H2O)(4)](ClO4)(6) (Re = Nd, Gd; Pro = proline) crystals
文献类型：期刊论文
| 作者 | Li, GT; Zhang, DS; Li, L; Tan, ZC; Wu, XM; Meng, SH |
| 刊名 | thermochimica acta
 |
| 出版日期 | 2001-07-20 |
| 卷号 | 375期号:1-2页码:125-130 |
| 关键词 | [Re-2(Pro)(6)(H2O)(4)]ClO4)(6) (Re = Nd heat capacity TG analysis combustion energy Gd Pro = proline) |
| 英文摘要 | the heat capacities of two solid complexes of rare-earth compounds with proline [re-2(pro)(6)(h2o)(4)](clo4)(6) (re = nd, gd; pro = proline. c5h9o2n), were measured with a high-precision automatic adiabatic calorimeter over the temperature range from 78 to 370 k, the heat capacity curves of the two complexes are smooth and similar in magnitude to each other except for a melting transition of [gd-2(pro)(6)(h2o)(4)](clo4)(6) that occurred in the temperature range of 340-346 k with a peak temperature of 342.48 +/- 0.01 k, the molar enthalpy and entropy of fusion of [gd-2(pro)(6)(h2o)(4)](clo4)(6) were determined to be 26.104 +/- 0.031 k j mol(-1) and 76.23 +/- 0.08 j k-1 mol(-1), respectively, on the basis of the heat capacity measurements. thermal decompositions of the two complexes were studied through the thermogravimetry (tg) experiments and possible mechanisms of the decompositions were suggested according to the tg analysis. the molar combustion energies of the two complexes were determined to he 17010 +/- 1.6 and 15630 +/- 1.5 j mol(-1) for [nd-2(pro)(6)(h2o)(4)](clo4)(6) and [gd-2(pro)(6)(h2o)(4)](clo4)(6), respectively, by means of oxygen-bomb calorimetric measurements. (c) 2001 elsevier science b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000169975500011 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138903]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Changde Normal Coll, Dept Chem, Changde 415000, Peoples R China 3.Wuhan Univ, Coll Chem & Environm Sci, Wuhan 430072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, GT,Zhang, DS,Li, L,et al. Low-temperature heat capacity and thermochemical study of [Re-2(Pro)(6)(H2O)(4)](ClO4)(6) (Re = Nd, Gd; Pro = proline) crystals[J]. thermochimica acta,2001,375(1-2):125-130. |
| APA | Li, GT,Zhang, DS,Li, L,Tan, ZC,Wu, XM,&Meng, SH.(2001).Low-temperature heat capacity and thermochemical study of [Re-2(Pro)(6)(H2O)(4)](ClO4)(6) (Re = Nd, Gd; Pro = proline) crystals.thermochimica acta,375(1-2),125-130. |
| MLA | Li, GT,et al."Low-temperature heat capacity and thermochemical study of [Re-2(Pro)(6)(H2O)(4)](ClO4)(6) (Re = Nd, Gd; Pro = proline) crystals".thermochimica acta 375.1-2(2001):125-130. |
入库方式： OAI收割
来源：大连化学物理研究所
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