中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 大连化学物理研究所
  3. 中国科学院大连化学物理研究所
Self-enrichment effect of neutral solute in CEC

文献类型：期刊论文

作者Zhang, WB; Zhu, J; Zhang, YK
刊名chemical journal of chinese universities-chinese
出版日期2001-09-01
卷号22期号:9页码:1477-1480
关键词CEC self-enrichment injecting time relaxation theory
英文摘要during the injection of neutral solute in cec, the partition equilibrium of solute between mobile phase and stationary phase will lead to an inhomogeneous distribution along column axes and bring on a self-enrichment effect. based on the relaxation theory, the transfer process of solute in column is dolt with by no-dimension method. the transfer equation forms an increasing series by degree. this equation is also solved with production function, and the second central moment of the profile is derived. compared to the common injecting process and self-enrichment, the expression which describes the effect of injecting time and retention value on enrichment is theoretically held and experimentally investigated with two drugs mephenytoin and benzoin. the results show that the longer the injecting time and the larger the capacity factor of solute, the stronger the self-enrichment effect. under the conditions of constant column efficiency, the self-enrichment effect can increase more than 10-fold detection sensitivity to the experimental solute.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, multidisciplinary
研究领域[WOS]chemistry
关键词[WOS]capillary electrochromatography
收录类别SCI
语种英语
WOS记录号WOS:000172215200010
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/138918]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Acad Sinica, Dalian Inst Chem Phys, Natl Chromatog Res & Anal Ctr, Dalian 116011, Peoples R China
推荐引用方式
GB/T 7714		 Zhang, WB,Zhu, J,Zhang, YK. Self-enrichment effect of neutral solute in CEC[J]. chemical journal of chinese universities-chinese,2001,22(9):1477-1480.
APA Zhang, WB,Zhu, J,&Zhang, YK.(2001).Self-enrichment effect of neutral solute in CEC.chemical journal of chinese universities-chinese,22(9),1477-1480.
MLA Zhang, WB,et al."Self-enrichment effect of neutral solute in CEC".chemical journal of chinese universities-chinese 22.9(2001):1477-1480.

入库方式： OAI收割

来源：大连化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。