Asymmetric cyclopropanation catalyzed by copper-Schiff's base complexes
文献类型：期刊论文
| 作者 | Li, ZN; Zheng, Z; Wan, BS; Chen, HL |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 2001-01-08 |
| 卷号 | 165期号:1-2页码:67-71 |
| 关键词 | cyclopropanation Schiff base Cu(II) complex diazoacetate asymmetric catalysis styrene |
| 英文摘要 | the asymmetric cyclopropanation of styrene with alkyl diazoacetate were performed with copper complexes of schiff bases, derived from substituted salicylaldehydes and a new chiral amino alcohol, as the catalysts. the electronic and steric properties, as well as the position of those substituents show obvious effects on the enantioselectivities, and ee higher than 98% were achieved under optimal conditions. (c) 2001 elsevier science b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | enantioselective cyclopropanation ; carbenoid reaction ; oxazoline ligands ; olefins ; diazoacetates ; derivatives ; styrene |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000166375300009 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138945]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, ZN,Zheng, Z,Wan, BS,et al. Asymmetric cyclopropanation catalyzed by copper-Schiff's base complexes[J]. journal of molecular catalysis a-chemical,2001,165(1-2):67-71. |
| APA | Li, ZN,Zheng, Z,Wan, BS,&Chen, HL.(2001).Asymmetric cyclopropanation catalyzed by copper-Schiff's base complexes.journal of molecular catalysis a-chemical,165(1-2),67-71. |
| MLA | Li, ZN,et al."Asymmetric cyclopropanation catalyzed by copper-Schiff's base complexes".journal of molecular catalysis a-chemical 165.1-2(2001):67-71. |
入库方式： OAI收割
来源：大连化学物理研究所
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