Studies on the carbonylation of carbon dioxide under single wavelength visible light irradiation
文献类型:期刊论文
作者 | Zhuang, JQ; Yin, JM; Gao, DB; Zheng, XF; Zhou, GY; Zhou, NZ; Wang, XS; Guo, XW |
刊名 | chemical journal of chinese universities-chinese
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出版日期 | 2001 |
卷号 | 22期号:1页码:75-77 |
关键词 | single wavelength visible light carbon dioxide carbonylation |
英文摘要 | it is the first time to report the carbonylation of cyclohexene with carbon dioxide under ambient conditions irradiated at single wavelength visible light. the effects of catalysts, the additives and different wavelength have been investigated, which indicated that the metal complexes such as cotpp and mntpp acted as catalyst of the carbonylation as well as sensitizer under the irradiation of special wavelength visible light. furthermore, when adding sodium proponiate to the solution, the catalysts such as pcfe would be activated and the formation of ester was promoted obviously. we also detected the quantum yield, of this reaction and found it can reach to 10(-2). as far as the quantum yield and taking good advantage of the energy from solar was concerned. hso3pcco was the better catalyst for the carbonylation. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, multidisciplinary |
研究领域[WOS] | chemistry |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000167569400020 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/139002] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Univ, Dept Chem & Chem Engn, Dalian 116622, Peoples R China 3.Dalian Univ Technol, Educ Minist Open Lab Carbon Resource Utilizat, Dalian 116012, Peoples R China |
推荐引用方式 GB/T 7714 | Zhuang, JQ,Yin, JM,Gao, DB,et al. Studies on the carbonylation of carbon dioxide under single wavelength visible light irradiation[J]. chemical journal of chinese universities-chinese,2001,22(1):75-77. |
APA | Zhuang, JQ.,Yin, JM.,Gao, DB.,Zheng, XF.,Zhou, GY.,...&Guo, XW.(2001).Studies on the carbonylation of carbon dioxide under single wavelength visible light irradiation.chemical journal of chinese universities-chinese,22(1),75-77. |
MLA | Zhuang, JQ,et al."Studies on the carbonylation of carbon dioxide under single wavelength visible light irradiation".chemical journal of chinese universities-chinese 22.1(2001):75-77. |
入库方式: OAI收割
来源:大连化学物理研究所
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