Inclusion properties of ball-shaped clathrate hosts and its application to preparing organic non-linear optical materials
文献类型：期刊论文
| 作者 | Guo, WS; Guo, F; Deng, M; Ge, CH; Liu, QT; Tian, ZY; Wang, SC; Zheng, QT |
| 刊名 | acta chimica sinica
 |
| 出版日期 | 2001 |
| 卷号 | 59期号:2页码:284-290 |
| 关键词 | inclusion compounds spherical host molecule phenol-type guest molecule SHG effect |
| 英文摘要 | this paper introduces design idea of spherical clathrate hosts which uses cedrol (1), brucine(2), 1,4 - diazabicyclo[2.2.2] octane (3) endowed of ball - shaped rigid molecular backbone as host molecules and phenol - type molecules such as phenol (4), o - cresol (5), m - cresol (6), p - cresol (7), 4 chrolophenol (8), 4 - methoxyphenol (9), 4 - hydroxylbenzaldehyde (10), 4 - nitrophenol (11) and maleicanhydride (12) used as guest molecules. we have carried out inclusion experiment using these hosts with phenol- type compounds. the formation of inclusion compounds were confirmed by means of powder xrd, and the molar ratios of inclusion compounds were determined by h-1 nmr, (1) + (4) 1:1,(1) + (5) 1:1, (7) 1:2, (3)+(8) 1:2, (3)+(9) 1:2, (3) + (11) 1:2 as results. the single crystal structure of a few typical. inclusion compounds was determined by x- ray diffraction analysis and showed that the variation of architectural structure characteristic of inclusion compounds depends on the volume size of the host molecules from channel type as with (1) + (5) and (2) + (11) to intercalate as with (3) + (11). the shg effect of the inclusion compound crystals was inspected by nd: yag laser and the results showed that a mass of prepared inclusion crystals exhibits non - linear optical property. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | ray crystal-structures ; design |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000167632500025 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139013]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaoning Univ, Inst Chem Sci & Engn, Shenyang 110036, Peoples R China 2.Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 3.Chinese Acad Med Sci, Inst Mat Med, Beijing 100050, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, WS,Guo, F,Deng, M,et al. Inclusion properties of ball-shaped clathrate hosts and its application to preparing organic non-linear optical materials[J]. acta chimica sinica,2001,59(2):284-290. |
| APA | Guo, WS.,Guo, F.,Deng, M.,Ge, CH.,Liu, QT.,...&Zheng, QT.(2001).Inclusion properties of ball-shaped clathrate hosts and its application to preparing organic non-linear optical materials.acta chimica sinica,59(2),284-290. |
| MLA | Guo, WS,et al."Inclusion properties of ball-shaped clathrate hosts and its application to preparing organic non-linear optical materials".acta chimica sinica 59.2(2001):284-290. |
入库方式： OAI收割
来源：大连化学物理研究所
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