Adsorption and decomposition of acetic acid on SmOx/Rh(100) model surface
文献类型：期刊论文
| 作者 | Ma, YS; Jiang, ZQ; Zhou, WP; Tan, DL; Zhai, RS; Bao, XH; Zhuang, SX |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2002-05-01 |
| 卷号 | 23期号:3页码:219-222 |
| 关键词 | acetic acid samarium oxide rhodium model surface thermal desorption spectroscopy high resolution electron energy loss spectroscopy |
| 英文摘要 | the adsorption and decomposition of acetic acid on smox/rh ( 100) model surface were investigated with high resolution electron energy loss spectroscopy (hreels) and thermal desorption spectroscopy (tds). the presence of smox weakened o-h bond in acetic acid molecules and therefore facilitated the formation of adsorbed acetate at 120 k. increasing the temperature, the addition of smox promoted further the decomposition of adsorbed acetate by weakening c-c bond. upon adsorption on smox/rh(100) surface at 120 k, most acetic acid molecules produced adsorbed acetate species via o-h bond cleavage. when the sample was heated to about 225 k, the decarboxylation of acetate occurs and co is the main product. the co and h, peaks were also observed at 417 k and 477 k, which could be attributed to reaction-limited products. the reaction mechanism was also discussed in this paper. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | rh(100) |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000176236500007 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139097]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, YS,Jiang, ZQ,Zhou, WP,et al. Adsorption and decomposition of acetic acid on SmOx/Rh(100) model surface[J]. chinese journal of catalysis,2002,23(3):219-222. |
| APA | Ma, YS.,Jiang, ZQ.,Zhou, WP.,Tan, DL.,Zhai, RS.,...&Zhuang, SX.(2002).Adsorption and decomposition of acetic acid on SmOx/Rh(100) model surface.chinese journal of catalysis,23(3),219-222. |
| MLA | Ma, YS,et al."Adsorption and decomposition of acetic acid on SmOx/Rh(100) model surface".chinese journal of catalysis 23.3(2002):219-222. |
入库方式： OAI收割
来源：大连化学物理研究所
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