State-to-state dynamics of H+HD -> H-2+D at 0.5 eV: A combined theoretical and experimental study
文献类型：期刊论文
| 作者 | Harich, SA; Dai, D; Yang, XM; Chao, SD; Skodje, RT |
| 刊名 | journal of chemical physics
 |
| 出版日期 | 2002-03-22 |
| 卷号 | 116期号:12页码:4769-4772 |
| 英文摘要 | the state-to-state dynamics of the h+hd-->h-2+d reaction at a collisional energy of 0.5 ev was studied experimentally using a crossed molecular beam apparatus using the h atom rydberg "tagging" time-of-flight detection scheme, and modeled theoretically using a converged quantum scattering calculation on the ground potential energy surface. the experimental results agreed very well with the theoretical calculations without considering the geometrical phase at this collisional energy. the results indicate that the h+hd reaction at this energy is dominated by a simple rebound mechanism along a collinear reaction path. both experimental and theoretical results show that the rotational state distribution of the h-2 product is strongly influenced by nuclear spin statistics. (c) 2002 american institute of physics. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | differential cross-sections ; potential-energy surface ; h+d-2->hd+d reaction ; quantum ; d+h2->hd+h ; scattering ; nuclei ; h-3 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000174363700005 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139107]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan 2.Chinese Acad Sci, Inst Chem Phys, Dalian, Peoples R China 3.Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan 4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China 5.Inst Mol Sci, Okazaki, Aichi 4448585, Japan 6.Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA |
| 推荐引用方式 GB/T 7714 | Harich, SA,Dai, D,Yang, XM,et al. State-to-state dynamics of H+HD -> H-2+D at 0.5 eV: A combined theoretical and experimental study[J]. journal of chemical physics,2002,116(12):4769-4772. |
| APA | Harich, SA,Dai, D,Yang, XM,Chao, SD,&Skodje, RT.(2002).State-to-state dynamics of H+HD -> H-2+D at 0.5 eV: A combined theoretical and experimental study.journal of chemical physics,116(12),4769-4772. |
| MLA | Harich, SA,et al."State-to-state dynamics of H+HD -> H-2+D at 0.5 eV: A combined theoretical and experimental study".journal of chemical physics 116.12(2002):4769-4772. |
入库方式： OAI收割
来源：大连化学物理研究所
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