Effects of solvents and quaternary ammonium ions in heteropolyoxotungstates on reaction-controlled phase-transfer catalysis for cyclohexene epoxidation
文献类型：期刊论文
| 作者 | Li, KL; Zhou, N; Xi, ZQ |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2002-03-01 |
| 卷号 | 23期号:2页码:125-126 |
| 关键词 | solvent heteropoyl compound quaternary ammonium ion reaction-controlled phase-transfer catalysis cyclohexene epoxidation |
| 英文摘要 | the effects of solvents and quaternary ammonium ions in q(3)[po4(wo3)(4)] (q= pi-c5h5nc16h33) on epoxidation of cyclohexene with 30% h2o2 were investigated. in the epoxidation, chloroform and t-butanol gave the best results. on the other hand, only the quaternary ammonium cations with suitable number of carbon atoms could form a reaction-controlled phase-transfer catalyst. in proper solvents, the initially insoluble catalyst could form soluble active species under the effect of h2o2 to lead to homogeneous catalytic epoxidation of olefins. when h2o2 was used up, the catalyst returned to its original structure and precipitated from the reaction medium. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | hydrogen-peroxide ; olefins |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000175026000009 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139111]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, KL,Zhou, N,Xi, ZQ. Effects of solvents and quaternary ammonium ions in heteropolyoxotungstates on reaction-controlled phase-transfer catalysis for cyclohexene epoxidation[J]. chinese journal of catalysis,2002,23(2):125-126. |
| APA | Li, KL,Zhou, N,&Xi, ZQ.(2002).Effects of solvents and quaternary ammonium ions in heteropolyoxotungstates on reaction-controlled phase-transfer catalysis for cyclohexene epoxidation.chinese journal of catalysis,23(2),125-126. |
| MLA | Li, KL,et al."Effects of solvents and quaternary ammonium ions in heteropolyoxotungstates on reaction-controlled phase-transfer catalysis for cyclohexene epoxidation".chinese journal of catalysis 23.2(2002):125-126. |
入库方式： OAI收割
来源：大连化学物理研究所
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