Clay-intercalated metal complex catalysts and their molecular recognition catalysis
文献类型：期刊论文
| 作者 | Tao, LX; Zou, DX |
| 刊名 | progress in chemistry
 |
| 出版日期 | 2002-05-01 |
| 卷号 | 14期号:3页码:200-206 |
| 关键词 | catalysts clay metal complexes heterogenization molecular recognition regioselectivity |
| 英文摘要 | the expandable layers of clay provide useful two dimensional hosts which facilitate introduction of catalytical active metal complexes by cation exchange and ligand exchange methods. intercalation of metal complexes into the interlamellar space of clay is an excellent method for homogeneous catalyst heterogenization. clay-intercalated metal complex catalysts display molecular-recognizing catalysis, such as shape selectivity, steroselectivity, regioselectivity. the application of these heterogenized catalysts in the asymmetric hydrogenation, regioselective hydrogenation, regioselective carbonylation and steroselective arylation is described in this review. clay-intercalated metal complex catalysts exhibit sufficiently high activity and selectivity to make them competitive to the homogeneous catalysts. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | titanium-pillared montmorillonite ; shape selective hydrogenation ; asymmetric hydrogenation ; smectite clay ; oxidation catalysts ; immobilization ; carbonylation ; hectorite ; olefins ; hydroesterification |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000177413200006 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139163]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tao, LX,Zou, DX. Clay-intercalated metal complex catalysts and their molecular recognition catalysis[J]. progress in chemistry,2002,14(3):200-206. |
| APA | Tao, LX,&Zou, DX.(2002).Clay-intercalated metal complex catalysts and their molecular recognition catalysis.progress in chemistry,14(3),200-206. |
| MLA | Tao, LX,et al."Clay-intercalated metal complex catalysts and their molecular recognition catalysis".progress in chemistry 14.3(2002):200-206. |
入库方式： OAI收割
来源：大连化学物理研究所
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