Synthesis, characterization and evaluation of a novel ester-bonded for reversed-phase HPLC
文献类型：期刊论文
| 作者 | Huang, XJ; Liu, XL; Wang, JD; Cong, RZ |
| 刊名 | chemical journal of chinese universities-chinese
 |
| 出版日期 | 2002-09-01 |
| 卷号 | 23期号:9页码:1684-1687 |
| 关键词 | silane coupling agent high performance liquid chromatography reversed phase packing ester-bonded stationary phase |
| 英文摘要 | a novel ester-bonded packing for reversed-phase hplc(rp-hplc) was synthesized by reacting octanoic acid with beta-(3, 4-epoxycyclohexyl) ethyltrimethoxy silane and then the intermediate product was coupled onto porous silica. characterization of the prepared packing was carried out with elemental analysis, solid-state c-13 nmr, and fourier transform infrared spectrometry. hydrophobicity, selectivity and silanophilic activity of the packing were evaluated by using organic components including acidic, basic and neutral analytes as probe molecules and methanol-water as binary mobile phase. the usage ranges of ph and stability of the packing were also evaluated. the results show that, the novel stationary phase has excellent. chromatographic properties and resist to hydrolysis between ph = 2. 5-7. 5, it can be used for the separation of basic solutes efficiently. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000178056800013 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139186]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, XJ,Liu, XL,Wang, JD,et al. Synthesis, characterization and evaluation of a novel ester-bonded for reversed-phase HPLC[J]. chemical journal of chinese universities-chinese,2002,23(9):1684-1687. |
| APA | Huang, XJ,Liu, XL,Wang, JD,&Cong, RZ.(2002).Synthesis, characterization and evaluation of a novel ester-bonded for reversed-phase HPLC.chemical journal of chinese universities-chinese,23(9),1684-1687. |
| MLA | Huang, XJ,et al."Synthesis, characterization and evaluation of a novel ester-bonded for reversed-phase HPLC".chemical journal of chinese universities-chinese 23.9(2002):1684-1687. |
入库方式： OAI收割
来源：大连化学物理研究所
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