Study on reforming natural gas-carbon dioxide-steam-oxygen to syngas: The role of rare earth additives
文献类型：期刊论文
| 作者 | Shi, KY; Xu, HY; Zhang, GL; Wang, YZ; Xu, GL; Wei, YD |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2002 |
| 卷号 | 23期号:1页码:15-18 |
| 关键词 | nickel-based catalyst rare earth additive methane activation adsorption syngas |
| 英文摘要 | the role of rare earth additives (ceo2 and la2o3) in ni-based catalysts has been investigated, and the activity and selectivity of the catalysts in reforming ch4-co2-h2o-o-2 to syngas have been studied. the results show that the la2o3-promoted catalysts increase the conversion of ch4 and the selectivity for h-2. the results of quantum chemistry calculation and xrd demonstrate that the la2o3 additive can decrease the intensity of diffraction peak of ni(111) crystal face of the reduced catalyst which makes its structure suitable for ch4 activation. the triodification of ni-based catalysts by re2o3 (ceo2) and mgo can increase d electron density of ni and impel d electron to pi* orbit, thus co2 is activated and its ability for carbon elimination is improved. the selectivity of the catalyst modified by ceo2 for co is higher than that by la2o3. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | surfaces ; methane |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000173814100004 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139190]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Harbin Inst Technol, Dept Appl Chem, Harbin 150001, Heilongjiang, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 3.Harbin Normal Univ, Dept Chem, Harbin 150080, Heilongjiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, KY,Xu, HY,Zhang, GL,et al. Study on reforming natural gas-carbon dioxide-steam-oxygen to syngas: The role of rare earth additives[J]. chinese journal of catalysis,2002,23(1):15-18. |
| APA | Shi, KY,Xu, HY,Zhang, GL,Wang, YZ,Xu, GL,&Wei, YD.(2002).Study on reforming natural gas-carbon dioxide-steam-oxygen to syngas: The role of rare earth additives.chinese journal of catalysis,23(1),15-18. |
| MLA | Shi, KY,et al."Study on reforming natural gas-carbon dioxide-steam-oxygen to syngas: The role of rare earth additives".chinese journal of catalysis 23.1(2002):15-18. |
入库方式： OAI收割
来源：大连化学物理研究所
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