Resonance Raman investigation of the short-time dynamics of the ultraviolet photodissociation of bromoform
文献类型：期刊论文
| 作者 | Li, YL; Lee, CW; Leung, KH; He, GZ; Phillips, DL |
| 刊名 | molecular physics
 |
| 出版日期 | 2002-08-01 |
| 卷号 | 100期号:16页码:2659-2663 |
| 英文摘要 | we report ultraviolet resonance raman spectra of bromoform (chbr3) in cyclohexane solution. the resonance raman spectra show significant intensity in the overtones of the nominal br-c-br symmetric bend (v(6)), the nominal h-c-br asymmetric bend (v(3)), the nominal br-c-br symmetric stretch (v(2)) and the nominal br-c-br asymmetric stretch (v(5)) vibrational modes suggesting that the short-time photodissociation dynamics have noticeable multidimensional character. the lack of strong combination bands between several of the franck-condon active modes suggests that more than one electronic transition contribute to the resonance raman spectra. we briefly discuss the ultraviolet short-time photodissociation dynamics of bromoform and the potential implications for the secondary photodissociation reactions of the initially formed chbr2 radical. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | magnetic circular-dichroism ; a-band photodissociation ; methylene iodide ; absorption-spectra ; intensity analysis ; gas-phase ; spectroscopy ; resolution ; chloroiodomethane ; solvation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000177250400008 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139225]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, YL,Lee, CW,Leung, KH,et al. Resonance Raman investigation of the short-time dynamics of the ultraviolet photodissociation of bromoform[J]. molecular physics,2002,100(16):2659-2663. |
| APA | Li, YL,Lee, CW,Leung, KH,He, GZ,&Phillips, DL.(2002).Resonance Raman investigation of the short-time dynamics of the ultraviolet photodissociation of bromoform.molecular physics,100(16),2659-2663. |
| MLA | Li, YL,et al."Resonance Raman investigation of the short-time dynamics of the ultraviolet photodissociation of bromoform".molecular physics 100.16(2002):2659-2663. |
入库方式： OAI收割
来源：大连化学物理研究所
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