Low-temperature heat capacity and thermodynamic properties of endo-tricyclo[5.2.1.0(2,6)]decane
文献类型：期刊论文
| 作者 | Kong, LG; Tan, ZC; Xu, J; Meng, SH; Bao, XH |
| 刊名 | journal of chemical thermodynamics
 |
| 出版日期 | 2003-12-01 |
| 卷号 | 35期号:12页码:1897-1904 |
| 关键词 | endo-tricyclo[5.2.1.0(2 heat capacity phase transition adiabatic calorimetry thermodynamic property 6)] idecane |
| 英文摘要 | endo-tricyclo[5.2.1.0(2,6)]decane (cas 6004-38-2) is an important intermediate compound for synthesizing diamantane. the lack of data on the thermodynamic properties of the compound limits its development and application. in this study, endo-tricyclo[5.2.1.0(2,6)]decane was synthesized and the low temperature heat capacities were measured with a high-precision adiabatic calorimeter in the temperature range from (80 to 360) k. two phase transitions were observed: the solid-solid phase transition in the temperature range from (198.79 to 210.27) k, with peak temperature 204.33 k; the solid-liquid phase transition in the temperature range from 333.76 k to 350.97 k, with peak temperature 345.28 k. the molar enthalpy increments, deltah(m), and entropy increments, deltas(m), of these phase transitions are deltah(m) = 2.57 kj(.)mol(-1) and deltas(m) = 12.57 j(.)k(-1.)mol(-1) for the solid-solid phase transition at 204.33 k, and, delta(fus)h(m) = 3.07 kj(.)mol(-1) and delta(fus)s(m) = 8.89 j(.)k(-1.)mol(-1) for the solid-liquid phase transition at 345.28 k. the thermal stability of the compound was investigated by thermogravimetric analysis. tg result shows that endo-tricyclo[5.2.1.0(2,6)]decane starts to sublime at 300 k and completely changes into vapor when the temperature reaches 423 k, reaching the maximal rate of weight loss at 408 k. (c) 2003 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | thermodynamics ; chemistry, physical |
| 研究领域[WOS] | thermodynamics ; chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000186987800001 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139240]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kong, LG,Tan, ZC,Xu, J,et al. Low-temperature heat capacity and thermodynamic properties of endo-tricyclo[5.2.1.0(2,6)]decane[J]. journal of chemical thermodynamics,2003,35(12):1897-1904. |
| APA | Kong, LG,Tan, ZC,Xu, J,Meng, SH,&Bao, XH.(2003).Low-temperature heat capacity and thermodynamic properties of endo-tricyclo[5.2.1.0(2,6)]decane.journal of chemical thermodynamics,35(12),1897-1904. |
| MLA | Kong, LG,et al."Low-temperature heat capacity and thermodynamic properties of endo-tricyclo[5.2.1.0(2,6)]decane".journal of chemical thermodynamics 35.12(2003):1897-1904. |
入库方式： OAI收割
来源：大连化学物理研究所
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