Effect of alkali promoters on catalytic performance of MnOx/ZrO2 for synthesis of methanol and isobutanol from syngas
文献类型：期刊论文
| 作者 | He, DP; Ding, YJ; Yin, HM; Wang, T; Zhu, HJ |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2003-02-01 |
| 卷号 | 24期号:2页码:111-114 |
| 关键词 | manganese oxide zirconia alkali promoter carbon monoxide hydrogenation isobutanol methanol |
| 英文摘要 | the influence of alkali promoters on the catalytic performance of mnox/zro2 for the selective synthesis of methanol and isobutanol from syngas was studied. the crystal structure, bet specific surface area and acidic properties of catalyst samples were measured by xrd, n-2 adsorption and nh3-tpd. it was found that the addition of alkali promoters had an obvious influence on the performance of mnox/zro2 catalyst. the selectivity for isobutanol increased in the order of na < li < rb < cs < k, which indicated that the moderately basic additives were desired for the formation of isobutanol on mnox/zro2 catalyst. the selectivity for isobutanol was strongly dependent on the anions of the potassium salts, increasing in the order of oh- < c2o42- < no3- < co32-, which revealed that a moderate alkali promotion was required. the catalyst of 1% k/mnox/zro2 (k2co3 as precursor) showed higher activity and selectivity for isobutanol under the conditions of 10 000 h(-1), 8.0 mpa and 673 k. the selectivity for alcohols and isobutanol was 74.8% and 16.3%, respectively. the results of characterization suggested that the acidic or basic property on the catalyst surface may play an important role in the formation of isobutanol. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | alcohol synthesis ; synthesis gas ; zirconium |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000181567900009 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139250]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Nat Gas Utilizat & Appl Catalysis Lab, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, DP,Ding, YJ,Yin, HM,et al. Effect of alkali promoters on catalytic performance of MnOx/ZrO2 for synthesis of methanol and isobutanol from syngas[J]. chinese journal of catalysis,2003,24(2):111-114. |
| APA | He, DP,Ding, YJ,Yin, HM,Wang, T,&Zhu, HJ.(2003).Effect of alkali promoters on catalytic performance of MnOx/ZrO2 for synthesis of methanol and isobutanol from syngas.chinese journal of catalysis,24(2),111-114. |
| MLA | He, DP,et al."Effect of alkali promoters on catalytic performance of MnOx/ZrO2 for synthesis of methanol and isobutanol from syngas".chinese journal of catalysis 24.2(2003):111-114. |
入库方式： OAI收割
来源：大连化学物理研究所
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