Low-temperature heat capacity and thermodynamic properties of 2-amino-4,6-dimethoxypyrimidine
文献类型：期刊论文
| 作者 | Sun, XH; Song, JR; Tan, ZC; Di, YY; Ma, HX; Wang, MH; Sun, LX |
| 刊名 | acta chimica sinica
 |
| 出版日期 | 2003-12-01 |
| 卷号 | 61期号:12页码:1897-1903 |
| 关键词 | 2-amino-4 6-dimethoxypyrimidine adiabatic calorimetry thermodynamic function different scanning calorimetry purity determination |
| 英文摘要 | the low-temperature heat capacities of 2-amino-4, 6-dimethoxypyrimidine ( c6h9n3o2) were precisely measured by an automated adiabatic calorimeter in the temperature range of 78 to 394 k. the sample was observed to melt at (370.97 +/- 0.02) k. on the basis of the heat-capacity measurements, the molar enthalpy and entropy of the phase transition as well as chemical purity of the substance were determined to be (29853. 91 +/- 9. 25) j (.) mol(-1), (80.45 +/- 0.03) j (.) mol(-1) (.) k-1 and 99.84%, respectively. the thermodynamic function of the compound were derived and reported at an interval of 5 k. the, further research of the melting process for this compound has been carried out by means of dsc technique. the result was in agreement with that. obtained from the measurements of heat capacities. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000187533900002 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139271]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.NW Univ Xian, Chem Engn Coll, Chem Res Inst, Xian 710069, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, XH,Song, JR,Tan, ZC,et al. Low-temperature heat capacity and thermodynamic properties of 2-amino-4,6-dimethoxypyrimidine[J]. acta chimica sinica,2003,61(12):1897-1903. |
| APA | Sun, XH.,Song, JR.,Tan, ZC.,Di, YY.,Ma, HX.,...&Sun, LX.(2003).Low-temperature heat capacity and thermodynamic properties of 2-amino-4,6-dimethoxypyrimidine.acta chimica sinica,61(12),1897-1903. |
| MLA | Sun, XH,et al."Low-temperature heat capacity and thermodynamic properties of 2-amino-4,6-dimethoxypyrimidine".acta chimica sinica 61.12(2003):1897-1903. |
入库方式： OAI收割
来源：大连化学物理研究所
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