Adsorption and decomposition of Mo(CO)(6) on thin Al2O3 films: fabrication of metallic molybdenum model catalyst
文献类型：期刊论文
| 作者 | Jiang, ZQ; Huang, WX; Jiao, J; Zhao, H; Tan, DL; Zhai, RS; Bao, XH |
| 刊名 | applied surface science
 |
| 出版日期 | 2004-05-15 |
| 卷号 | 229期号:1-4页码:43-50 |
| 关键词 | molybdenum hexacarbonyl molybdenum alumina thermal desorption spectroscopy X-ray photoelectron spectroscopy |
| 英文摘要 | an ultra-thin and homogeneous alumina film is prepared by deposition and oxidation of aluminum on a platinum substrate under ultrahigh vacuum conditions. auger electron spectroscopy (aes), x-ray photoelectron spectroscopy (xps) and high-resolution electron-energy-loss spectroscopy (hreels) demonstrate that this film is completely stoichiometric and characteristic of al2o3. temperature-programmed desorption (tpd) and xps characterization show that the mo(co)(6) decomposes and leaves molybdenum with c and o contaminants on the al2o3 film at 700 k. subsequent heat treatment at 1200 k results in the formation of a model surface of metallic-molybdenum-modified alumina, which could be applied to simulate the activation of ch4. (c) 2004 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; materials science, coatings & films ; physics, applied ; physics, condensed matter |
| 研究领域[WOS] | chemistry ; materials science ; physics |
| 关键词[WOS] | x-ray photoelectron ; alumina catalysts ; surface-chemistry ; spectroscopic characterization ; propene metathesis ; hexacarbonyl ; reduction ; photodissociation ; carbonyls ; energy |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000221680100009 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139285]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, ZQ,Huang, WX,Jiao, J,et al. Adsorption and decomposition of Mo(CO)(6) on thin Al2O3 films: fabrication of metallic molybdenum model catalyst[J]. applied surface science,2004,229(1-4):43-50. |
| APA | Jiang, ZQ.,Huang, WX.,Jiao, J.,Zhao, H.,Tan, DL.,...&Bao, XH.(2004).Adsorption and decomposition of Mo(CO)(6) on thin Al2O3 films: fabrication of metallic molybdenum model catalyst.applied surface science,229(1-4),43-50. |
| MLA | Jiang, ZQ,et al."Adsorption and decomposition of Mo(CO)(6) on thin Al2O3 films: fabrication of metallic molybdenum model catalyst".applied surface science 229.1-4(2004):43-50. |
入库方式： OAI收割
来源：大连化学物理研究所
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