Capillary gas chromatographic column switching-backflushing technique for the analysis of aromatics in aviation kerosene by normalization method
文献类型：期刊论文
| 作者 | Shen, WJ; Wang, HW; Zhao, JH; Wang, ZP; Wang, FY; Guan, YF |
| 刊名 | chinese journal of analytical chemistry
 |
| 出版日期 | 2004-07-01 |
| 卷号 | 32期号:7页码:953-957 |
| 关键词 | column switching-backflushing technique two-dimensional gas chromatography aviation kerosene aromatics normalization method |
| 英文摘要 | the aromatics in aviation kerosene was separated and analyzed by capillary gas chromatography using column switching-backflushing technique. the aromatics having carbon number of n are retained after n-cn+3 on the ffap pre-column, and were cut and back flushed after the elution of n-cn+3, onto a nonpolar analytical column and were separated according to their boiling points. since the early eluting components from. the pre-column, and the aromatics and heavier saturates from the analytical column are all directed to the same flame ionization detector through a "t" piece, a factor corrected normalization method can be applied for quantitation. the resistance of the resistor after the pre-column is designed 6 times higher than that of analytical column, resulting in 5.4 times higher carrier gas flow rate after backflushing. the chromatographic bands are compressed, enhancing the sensitivity 2 times more for aromatics and heavier saturates. two aviation kerosene samples were analyzed and the switching time window is more than +/- 18 s. the error of reproducibility of the analysis is less than or equal to4.0%. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | liquid-chromatography ; gasoline ; mixtures |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000223324000028 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139298]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China 2.Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen, WJ,Wang, HW,Zhao, JH,et al. Capillary gas chromatographic column switching-backflushing technique for the analysis of aromatics in aviation kerosene by normalization method[J]. chinese journal of analytical chemistry,2004,32(7):953-957. |
| APA | Shen, WJ,Wang, HW,Zhao, JH,Wang, ZP,Wang, FY,&Guan, YF.(2004).Capillary gas chromatographic column switching-backflushing technique for the analysis of aromatics in aviation kerosene by normalization method.chinese journal of analytical chemistry,32(7),953-957. |
| MLA | Shen, WJ,et al."Capillary gas chromatographic column switching-backflushing technique for the analysis of aromatics in aviation kerosene by normalization method".chinese journal of analytical chemistry 32.7(2004):953-957. |
入库方式： OAI收割
来源：大连化学物理研究所
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