中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Crossed molecular beam studies of the fluorine atom reaction with trans-1,3-butadiene

文献类型:期刊论文

作者Gu, QL; Wang, XY; Shen, GL; Yang, CX; Ran, Q; Yang, XM
刊名chinese journal of chemical physics
出版日期2004-02-01
卷号17期号:1页码:15-20
关键词crossed molecular beam trans-1 fluorine atom 3-butadiene
英文摘要the fluorine atom reaction with trans-1,3-butadiene has been investigated by using the crossed molecular beam method. signals at mass 72, 46 and 33 have been observed. a single reaction channel c4h5f + h is observed for this reaction channel. product angular distributions and velocity distributions are determined. the experimental results indicate that the channel mainly proceeds via a long-lived complex at a collisional energy of 23.8 kj/mol. the collision complex is likely formed with the f atom attacking the delocalized electrons in the direction perpendicular to the molecular plane of trans-1,3-butadiene molecule.
WOS标题词science & technology ; physical sciences
类目[WOS]physics, atomic, molecular & chemical
研究领域[WOS]physics
关键词[WOS]scattering
收录类别SCI
语种英语
WOS记录号WOS:000220151200005
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/139331]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
2.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan
3.Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan
推荐引用方式
GB/T 7714
Gu, QL,Wang, XY,Shen, GL,et al. Crossed molecular beam studies of the fluorine atom reaction with trans-1,3-butadiene[J]. chinese journal of chemical physics,2004,17(1):15-20.
APA Gu, QL,Wang, XY,Shen, GL,Yang, CX,Ran, Q,&Yang, XM.(2004).Crossed molecular beam studies of the fluorine atom reaction with trans-1,3-butadiene.chinese journal of chemical physics,17(1),15-20.
MLA Gu, QL,et al."Crossed molecular beam studies of the fluorine atom reaction with trans-1,3-butadiene".chinese journal of chemical physics 17.1(2004):15-20.

入库方式: OAI收割

来源:大连化学物理研究所

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