Crossed molecular beam studies of the fluorine atom reaction with trans-1,3-butadiene
文献类型:期刊论文
作者 | Gu, QL; Wang, XY; Shen, GL; Yang, CX; Ran, Q; Yang, XM |
刊名 | chinese journal of chemical physics
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出版日期 | 2004-02-01 |
卷号 | 17期号:1页码:15-20 |
关键词 | crossed molecular beam trans-1 fluorine atom 3-butadiene |
英文摘要 | the fluorine atom reaction with trans-1,3-butadiene has been investigated by using the crossed molecular beam method. signals at mass 72, 46 and 33 have been observed. a single reaction channel c4h5f + h is observed for this reaction channel. product angular distributions and velocity distributions are determined. the experimental results indicate that the channel mainly proceeds via a long-lived complex at a collisional energy of 23.8 kj/mol. the collision complex is likely formed with the f atom attacking the delocalized electrons in the direction perpendicular to the molecular plane of trans-1,3-butadiene molecule. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | physics, atomic, molecular & chemical |
研究领域[WOS] | physics |
关键词[WOS] | scattering |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000220151200005 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/139331] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan 3.Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan |
推荐引用方式 GB/T 7714 | Gu, QL,Wang, XY,Shen, GL,et al. Crossed molecular beam studies of the fluorine atom reaction with trans-1,3-butadiene[J]. chinese journal of chemical physics,2004,17(1):15-20. |
APA | Gu, QL,Wang, XY,Shen, GL,Yang, CX,Ran, Q,&Yang, XM.(2004).Crossed molecular beam studies of the fluorine atom reaction with trans-1,3-butadiene.chinese journal of chemical physics,17(1),15-20. |
MLA | Gu, QL,et al."Crossed molecular beam studies of the fluorine atom reaction with trans-1,3-butadiene".chinese journal of chemical physics 17.1(2004):15-20. |
入库方式: OAI收割
来源:大连化学物理研究所
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