Liquid-phase catalytic synthesis of 2,5-dimethyl-2,4-hexadiene by condensation of iso-butyl aldehyde with tert-butyl alcohol over solid acidic
文献类型：期刊论文
| 作者 | Wang, H; Liu, ZM; Sun, CL; Wang, GW |
| 刊名 | catalysis today
 |
| 出版日期 | 2004-09-01 |
| 卷号 | 93-5页码:425-431 |
| 关键词 | 2 HZSM-5 molecular sieve iso-butyl aldehyde liquid-phase Prins reaction tert-butyl alcohol 5-dimethyl-2 4-hexadiene |
| 英文摘要 | several solid acidic catalysts have been investigated for the prins condensation of iso-butyl aldehyde with tert-butyl alcohol in a liquid-phase reaction. the results demonstrate that acidic molecular sieves are effective catalysts for the condensation reaction, and hzsm-5 molecular sieves possessed strong enough acidity and proper channel systems exhibit high catalytic performance. solvent polarity and solvent-active site interaction would significantly affect the aldehyde conversion and the 2,5-dimethyl-2,4-hexadiene selectivity. the iso-butyl aldehyde to tert-buoh ratio, catalyst amount, solvent amount, reaction temperature, reaction time, si/al ratio of hzsm-5 molecular sieves, catalytic performance of different solid acids, and side-reactions in the system are studied. up to 78.6% iso-butyl aldehyde conversion is obtained with a 57.8% 2,5-dimethyl-2,4-hexadiene yield over hzsm-5 with si/al of 39 after 8 h at 160degreesc, which provides a useful and economical potential industrial application way on a large scale to manufacture 2,5-dimethyl-2,4-hexadiene. (c) 2004 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 收录类别 | ISTP ; SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000223973200060 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139352]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Nat Gas Utilizat & Appl Catalysis Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, H,Liu, ZM,Sun, CL,et al. Liquid-phase catalytic synthesis of 2,5-dimethyl-2,4-hexadiene by condensation of iso-butyl aldehyde with tert-butyl alcohol over solid acidic[J]. catalysis today,2004,93-5:425-431. |
| APA | Wang, H,Liu, ZM,Sun, CL,&Wang, GW.(2004).Liquid-phase catalytic synthesis of 2,5-dimethyl-2,4-hexadiene by condensation of iso-butyl aldehyde with tert-butyl alcohol over solid acidic.catalysis today,93-5,425-431. |
| MLA | Wang, H,et al."Liquid-phase catalytic synthesis of 2,5-dimethyl-2,4-hexadiene by condensation of iso-butyl aldehyde with tert-butyl alcohol over solid acidic".catalysis today 93-5(2004):425-431. |
入库方式： OAI收割
来源：大连化学物理研究所
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