Dibenzothiophene hydrodesulfurization activity and surface sites of silica-supported MoP, Ni2P, and Ni-Mo-P catalysts
文献类型：期刊论文
| 作者 | Sun, FX; Wu, WC; Wu, ZL; Guo, J; Wei, ZB; Yang, YX; Jiang, ZX; Tian, FP; Li, C |
| 刊名 | journal of catalysis
 |
| 出版日期 | 2004-12-10 |
| 卷号 | 228期号:2页码:298-310 |
| 关键词 | hydrodesulfurization transition metal phosphides MoP Ni2P NiMoP dibenzothiophene IR spectroscopy CO adsorption |
| 英文摘要 | silica-supported binary and ternary phosphides, mop/sio2, ni2p/sio2, and ni-mo-p/sio2 have been prepared and characterized by x-ray diffraction (xrd), bet surface area, co chemisorption, transmission electron microscopy (tem), and infrared spectroscopy (ir). the hydrodesulfurization (hds) activities of dibenzothiophene (dbt) were measured and compared at 593 k and 3.0 mpa for mop/sio2, ni2p/sio2, and ni-mo-p/sio2 catalysts with different mo and ni loadings. the activities of the phosphides follow the order ni2p/sio2 > ni-mo-p/sio2 > mop/sio2. the ni sites in the ni-mo-p/sio2 catalysts play a major role in the conversion of dbt, and the activity of the catalysts increases with increasing ni content. this is different from sulfides, nitrides, and carbides, as no synergetic effect is observed between the phosphided ni and the mo atoms. the surface of these phosphide catalysts is partially sulfided forming a surface phosphosulfide phase, while the bulk structure of the phosphides is maintained in the hds reactions. (c) 2004 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | transition-metal phosphides ; magnetic-resonance spectroscopy ; carbon-monoxide ; thiophene hydrodesulfurization ; molybdenum phosphide ; tungsten phosphide ; phosphorus promotion ; co adsorption ; nickel ; hydrodenitrogenation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000225661200005 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139379]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, FX,Wu, WC,Wu, ZL,et al. Dibenzothiophene hydrodesulfurization activity and surface sites of silica-supported MoP, Ni2P, and Ni-Mo-P catalysts[J]. journal of catalysis,2004,228(2):298-310. |
| APA | Sun, FX.,Wu, WC.,Wu, ZL.,Guo, J.,Wei, ZB.,...&Li, C.(2004).Dibenzothiophene hydrodesulfurization activity and surface sites of silica-supported MoP, Ni2P, and Ni-Mo-P catalysts.journal of catalysis,228(2),298-310. |
| MLA | Sun, FX,et al."Dibenzothiophene hydrodesulfurization activity and surface sites of silica-supported MoP, Ni2P, and Ni-Mo-P catalysts".journal of catalysis 228.2(2004):298-310. |
入库方式： OAI收割
来源：大连化学物理研究所
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