Study, on thermochemistry of room temperature ionic liquid 1. Solution enthalpy of EMIES and Pitzer's parameters
文献类型:期刊论文
作者 | Tan, ZC; Zhang, ZH; Sun, LX; Xu, WG; Xu, F; Yang, JZ; Zhang, T |
刊名 | acta chimica sinica |
出版日期 | 2004-11-14 |
卷号 | 62期号:21页码:2161-2164 |
关键词 | room temperature ionic liquid EMIES solution enthalpy apparent relative molar enthalpy Pitzer's parameter isoperibol calorimeter |
英文摘要 | using the solution reaction isoperibol calorimeter, the molar solution enthalpies of room temperature ionic liquid, 1-ethyl-3-methylimidazolium ethyl sulfate (emies), with various molalities were determined at t = 303.150 k in water. according to pitzer' s electrolyte solution theory, the molar solution enthalpy of emies at infinite dilution, delta(s)h(m)(0), and pitzer's parameters: beta(mx)((0)l), beta(mx)((1)l) and c-mx(phil) were obtained. then the values of apparent relative molar enthalpy l-phi, and relative partial molar enthalpy of solvent and solute (emies), (l) over bar (1) and (l) over bar (2) were calculated, respectively. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, multidisciplinary |
研究领域[WOS] | chemistry |
关键词[WOS] | calorimeter ; chloride |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000225048900006 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/139381] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China |
推荐引用方式 GB/T 7714 | Tan, ZC,Zhang, ZH,Sun, LX,et al. Study, on thermochemistry of room temperature ionic liquid 1. Solution enthalpy of EMIES and Pitzer's parameters[J]. acta chimica sinica,2004,62(21):2161-2164. |
APA | Tan, ZC.,Zhang, ZH.,Sun, LX.,Xu, WG.,Xu, F.,...&Zhang, T.(2004).Study, on thermochemistry of room temperature ionic liquid 1. Solution enthalpy of EMIES and Pitzer's parameters.acta chimica sinica,62(21),2161-2164. |
MLA | Tan, ZC,et al."Study, on thermochemistry of room temperature ionic liquid 1. Solution enthalpy of EMIES and Pitzer's parameters".acta chimica sinica 62.21(2004):2161-2164. |
入库方式: OAI收割
来源:大连化学物理研究所
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