中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
The effect of acidity and pore structure of catalysts on the dehydroisomerization of n-butane to isobutene

文献类型:期刊论文

作者Wei, Y; Wang, G; Liu, Z; Xu, L; Xie, P; VanSteen, E; Claeys, M; Callanan, LH
刊名recent advances in the science and technology of zeolites and related materials, pts a - c
出版日期2004
卷号154页码:2359-2363
英文摘要four molecular sieves of alpo-11 and sapo-5, 11, 34 were synthesized and characterized. the results showed the differences of acidity and porous structure. the four samples were modified by pd and used in the direct transformation of n-butane to isobutene. pd/aipo-11, pd/sapo-5 and pd/sapo-34 showed low catalytic activity and poor selectivity for isobutene, while pd/sapo-11 showed relatively high activity and high isobutene selectivity. the effect of acidity and porous structure on the support pd and the catalytic performance were discussed. medium strong acidity and suitable pore geometry were necessary in this reaction.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, physical ; materials science, multidisciplinary
研究领域[WOS]chemistry ; materials science
关键词[WOS]silicoaluminophosphate molecular-sieves ; reaction-mechanism ; hydrocarbon formation ; co-reaction ; hydroisomerization ; sapo-34 ; octane ; isomerization ; hydrocracking ; pt/sapo-11
收录类别ISTP ; SCI
语种英语
WOS记录号WOS:000227357202032
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/139385]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Nat Gas Utilizat & Appl Catalysis Lab, Dalian 116023, Peoples R China
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GB/T 7714
Wei, Y,Wang, G,Liu, Z,et al. The effect of acidity and pore structure of catalysts on the dehydroisomerization of n-butane to isobutene[J]. recent advances in the science and technology of zeolites and related materials, pts a - c,2004,154:2359-2363.
APA Wei, Y.,Wang, G.,Liu, Z.,Xu, L.,Xie, P.,...&Callanan, LH.(2004).The effect of acidity and pore structure of catalysts on the dehydroisomerization of n-butane to isobutene.recent advances in the science and technology of zeolites and related materials, pts a - c,154,2359-2363.
MLA Wei, Y,et al."The effect of acidity and pore structure of catalysts on the dehydroisomerization of n-butane to isobutene".recent advances in the science and technology of zeolites and related materials, pts a - c 154(2004):2359-2363.

入库方式: OAI收割

来源:大连化学物理研究所

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