中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
THE H-1, C-13 NMR STUDIES ON ALKALOID PLATINUM(II) COMPLEXES

文献类型:期刊论文

作者Yang Zhenyun; Han Xiuwen; Hu Jiehan; Chen Huilin
刊名acta physico-chimica sinica
出版日期1988
卷号4期号:1页码:32-36
英文摘要the c-13 and h-1 nmr spectra of antitumor alkaloid platinum complexes such as caffeine, theophylline and theobromine platinum (ii)complexes were recorded. the h-1, c-13 chemical shifts and carbon hydrogen coupling conatants were obtained for these alkaloids and their platinum complexes. compating the variations of 61, and 8c in, the uganda before, and after coordination and combining with the determination of carbon platinum and hydrogen platinum coupling constants, we find that the alkaloids coordinate to platinum unidentately the coordination site is the double bond nitrogen atom on the five membered imidazole ring, the pla tinum (ii) is coordinated with three chloride anions and one alkaloid ligand to form a mononuclear complex anion (ptlcl3)(-). by heterortuclear proton selected decoupling technique, all the h-1 and c-13 nur spectral linen were assigned.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
收录类别SCI
语种英语
WOS记录号WOS:000207571200007
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/139406]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Acad Sinica, Dalian Inst Chem Phys, Dalian, Peoples R China
推荐引用方式
GB/T 7714
Yang Zhenyun,Han Xiuwen,Hu Jiehan,et al. THE H-1, C-13 NMR STUDIES ON ALKALOID PLATINUM(II) COMPLEXES[J]. acta physico-chimica sinica,1988,4(1):32-36.
APA Yang Zhenyun,Han Xiuwen,Hu Jiehan,&Chen Huilin.(1988).THE H-1, C-13 NMR STUDIES ON ALKALOID PLATINUM(II) COMPLEXES.acta physico-chimica sinica,4(1),32-36.
MLA Yang Zhenyun,et al."THE H-1, C-13 NMR STUDIES ON ALKALOID PLATINUM(II) COMPLEXES".acta physico-chimica sinica 4.1(1988):32-36.

入库方式: OAI收割

来源:大连化学物理研究所

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