THE H-1, C-13 NMR STUDIES ON ALKALOID PLATINUM(II) COMPLEXES
文献类型:期刊论文
作者 | Yang Zhenyun; Han Xiuwen; Hu Jiehan; Chen Huilin |
刊名 | acta physico-chimica sinica
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出版日期 | 1988 |
卷号 | 4期号:1页码:32-36 |
英文摘要 | the c-13 and h-1 nmr spectra of antitumor alkaloid platinum complexes such as caffeine, theophylline and theobromine platinum (ii)complexes were recorded. the h-1, c-13 chemical shifts and carbon hydrogen coupling conatants were obtained for these alkaloids and their platinum complexes. compating the variations of 61, and 8c in, the uganda before, and after coordination and combining with the determination of carbon platinum and hydrogen platinum coupling constants, we find that the alkaloids coordinate to platinum unidentately the coordination site is the double bond nitrogen atom on the five membered imidazole ring, the pla tinum (ii) is coordinated with three chloride anions and one alkaloid ligand to form a mononuclear complex anion (ptlcl3)(-). by heterortuclear proton selected decoupling technique, all the h-1 and c-13 nur spectral linen were assigned. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000207571200007 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/139406] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Acad Sinica, Dalian Inst Chem Phys, Dalian, Peoples R China |
推荐引用方式 GB/T 7714 | Yang Zhenyun,Han Xiuwen,Hu Jiehan,et al. THE H-1, C-13 NMR STUDIES ON ALKALOID PLATINUM(II) COMPLEXES[J]. acta physico-chimica sinica,1988,4(1):32-36. |
APA | Yang Zhenyun,Han Xiuwen,Hu Jiehan,&Chen Huilin.(1988).THE H-1, C-13 NMR STUDIES ON ALKALOID PLATINUM(II) COMPLEXES.acta physico-chimica sinica,4(1),32-36. |
MLA | Yang Zhenyun,et al."THE H-1, C-13 NMR STUDIES ON ALKALOID PLATINUM(II) COMPLEXES".acta physico-chimica sinica 4.1(1988):32-36. |
入库方式: OAI收割
来源:大连化学物理研究所
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