中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Preparation of polyacrylate-like capillary monolithic-column and its application to p-CEC

文献类型:期刊论文

作者Yang, JJ; Zhang, K; Gao, RY; Znang, YK; Yan, C
刊名chemical journal of chinese universities-chinese
出版日期2004-08-01
卷号25期号:8页码:1445-1447
关键词polymers capillary monolithic-column pressurized-capillary electrochromatography(p-CEC)
英文摘要a novel monolithic stationary phase with long alkyl chain ligands was introduced and evaluated in pressurized capillary electrochromatography (p-cec) by using a mixture of neutral and charged compounds. the capillary monolithic-column was prepared by in situ copolymerization of ethylene dimethacrylate, alkyl alcohol and 2-acrylamido-2-methyl-1-propanesulfonic acid in a quadruple porogenic solvent consisting of 1, 4-butanediol/cyclohexanol/docecanol/water. effects of experimental parameters in p-cec, such as pressure and electrical field strength, on the separation were investigated. the baseline separation of the components in the mixture was achieved. the monolithic column can be used as an alternative to the conventional capillary column such as the reversed phase ods.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, multidisciplinary
研究领域[WOS]chemistry
关键词[WOS]rigid polymer monoliths ; stationary phases ; separation media ; electrochromatography ; performance ; alkyl
收录类别SCI
语种英语
WOS记录号WOS:000223524600016
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/139467]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Unimicro Analyt Technol Co Ltd, Shanghai 201203, Peoples R China
2.Beijing Univ Chem Technol, Anal Ctr, Beijing 100029, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116011, Peoples R China
4.Nankai Univ, Inst Element Organ Chem, Tianjin 300071, Peoples R China
推荐引用方式
GB/T 7714
Yang, JJ,Zhang, K,Gao, RY,et al. Preparation of polyacrylate-like capillary monolithic-column and its application to p-CEC[J]. chemical journal of chinese universities-chinese,2004,25(8):1445-1447.
APA Yang, JJ,Zhang, K,Gao, RY,Znang, YK,&Yan, C.(2004).Preparation of polyacrylate-like capillary monolithic-column and its application to p-CEC.chemical journal of chinese universities-chinese,25(8),1445-1447.
MLA Yang, JJ,et al."Preparation of polyacrylate-like capillary monolithic-column and its application to p-CEC".chemical journal of chinese universities-chinese 25.8(2004):1445-1447.

入库方式: OAI收割

来源:大连化学物理研究所

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