ROLE OF CARRIERS IN THE SELECTIVE HYDROGENATION OF CYCLOPENTADIENE OVER SUPPORTED PALLADIUM CATALYSIS
文献类型：期刊论文
| 作者 | Zhang Shulin; Xu Jun; Liao Shijian; Yu Daorong; Zhang Yiping |
| 刊名 | acta physico-chimica sinica
 |
| 出版日期 | 1989 |
| 卷号 | 5期号:1页码:38-43 |
| 英文摘要 | several supported palladium catalysts were prepared and thier effects on the kinetic behaviors in the selective hydrogenation of cyclopentadiene were studied. experiments show that cyclopentadiene inhibits the hydrogenation of cyclopentene. data based on kinetic analysis indicate that the coordination of cyclopentadiene is much stronger than that of cyclopentene which should be the main factor of this inhibition reaction. catalyst carriers via thier ligand effects can influence the ratio of the coordination equilibrium constants k-d/k-e and the rate constants k-2/k-4, which in turn change the selectivities and activities of catalyets. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000207572000009 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139488]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Acad Sinica, Dalian Inst Chem Phys, Dalian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Shulin,Xu Jun,Liao Shijian,et al. ROLE OF CARRIERS IN THE SELECTIVE HYDROGENATION OF CYCLOPENTADIENE OVER SUPPORTED PALLADIUM CATALYSIS[J]. acta physico-chimica sinica,1989,5(1):38-43. |
| APA | Zhang Shulin,Xu Jun,Liao Shijian,Yu Daorong,&Zhang Yiping.(1989).ROLE OF CARRIERS IN THE SELECTIVE HYDROGENATION OF CYCLOPENTADIENE OVER SUPPORTED PALLADIUM CATALYSIS.acta physico-chimica sinica,5(1),38-43. |
| MLA | Zhang Shulin,et al."ROLE OF CARRIERS IN THE SELECTIVE HYDROGENATION OF CYCLOPENTADIENE OVER SUPPORTED PALLADIUM CATALYSIS".acta physico-chimica sinica 5.1(1989):38-43. |
入库方式： OAI收割
来源：大连化学物理研究所
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