Heat capacity and thermodynamic properties of 2,4-dichlorobenzaldehyde (C7H4Cl2O)
文献类型：期刊论文
| 作者 | Wang, SX; Tan, ZC; Di, YY; Xu, F; Zhang, HT; Sun, LX; Zhang, T |
| 刊名 | journal of chemical thermodynamics
 |
| 出版日期 | 2004-05-01 |
| 卷号 | 36期号:5页码:393-399 |
| 关键词 | 2 heat capacity adiabatic calorimetry purity determination DSC analysis 4-dichlorobenzaldehyde |
| 英文摘要 | heat capacities of 2,4-dichlorobenzaldehyde have been measured with a high-precision automatic adiabatic calorimeter over the temperature range from (79 to 371) k. the melting temperature, molar enthalpy, and entropy of fusion were determined by the heat capacity measurements to be (347.24 +/- 0.13) k, (20468 +/- 19) j (.) mol(-1), and (58.94 +/- 0.04) j (.) k-1 (.) mol(-1), respectively. the melting temperatures for the sample and the absolutely pure compound have been obtained from fractional melting experiments to be (347.230 and 347.619) k, respectively, and the chemical purity of the sample was calculated to be 0.9921 mol fraction according to the van't hoff equation. moreover, the solid-to-liquid phase transition of the substance was further investigated by using dsc technique. the results obtained from the heat capacity measurements were in agreement with those from the dsc analysis. (c) 2004 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | thermodynamics ; chemistry, physical |
| 研究领域[WOS] | thermodynamics ; chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000221042400005 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139519]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, SX,Tan, ZC,Di, YY,et al. Heat capacity and thermodynamic properties of 2,4-dichlorobenzaldehyde (C7H4Cl2O)[J]. journal of chemical thermodynamics,2004,36(5):393-399. |
| APA | Wang, SX.,Tan, ZC.,Di, YY.,Xu, F.,Zhang, HT.,...&Zhang, T.(2004).Heat capacity and thermodynamic properties of 2,4-dichlorobenzaldehyde (C7H4Cl2O).journal of chemical thermodynamics,36(5),393-399. |
| MLA | Wang, SX,et al."Heat capacity and thermodynamic properties of 2,4-dichlorobenzaldehyde (C7H4Cl2O)".journal of chemical thermodynamics 36.5(2004):393-399. |
入库方式： OAI收割
来源：大连化学物理研究所
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