Thermodynamic investigation on the azeotropic mixture composed of water plus n-propanol plus benzene
文献类型：期刊论文
| 作者 | Nan, ZD; Tan, ZC |
| 刊名 | thermochimica acta
 |
| 出版日期 | 2004-04-08 |
| 卷号 | 413期号:1-2页码:267-272 |
| 关键词 | heat capacity water n-propanol benzene low temperature adiabatic calorimetry |
| 英文摘要 | molar heat capacity of the azeotropic mixture composed of water, n-propanol, and benzene was measured by an adiabatic calorimeter from 79 to 320 k. the glass transition and melting processes of the mixture were determined based on the curve of the heat capacity with respect to temperature. the glass transition occurred at 101.920 k. the melting processes took place in temperature ranges 258-268 and 268-279 k. the corresponding melting enthalpies and entropies were calculated to be 1.474 kj mol(-1), 5.508 j k-1 mol(-1); 6.144 kj mol(-1), 22.28 j k-1 mol(-1), respectively. the thermodynamic functions and the excess thermodynamic functions of the mixture relative to temperature 298.15 k were derived based on the relationships of the thermodynamic functions and the function of the measured heat capacity with respect to temperature. (c) 2003 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | extractive distillation ; heat-capacities ; calorimeter ; ether |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000220258500031 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139522]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Qufu Normal Univ, Dept Chem, Shandong 273165, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Nan, ZD,Tan, ZC. Thermodynamic investigation on the azeotropic mixture composed of water plus n-propanol plus benzene[J]. thermochimica acta,2004,413(1-2):267-272. |
| APA | Nan, ZD,&Tan, ZC.(2004).Thermodynamic investigation on the azeotropic mixture composed of water plus n-propanol plus benzene.thermochimica acta,413(1-2),267-272. |
| MLA | Nan, ZD,et al."Thermodynamic investigation on the azeotropic mixture composed of water plus n-propanol plus benzene".thermochimica acta 413.1-2(2004):267-272. |
入库方式： OAI收割
来源：大连化学物理研究所
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