Study on organic-inorganic hybrid L-Rh/SiO2 catalysts for hydroformylation of olefins catalytic performance and characterization of PPh3-Rh/SiO2 catalyst
文献类型：期刊论文
| 作者 | Zhu, HJ; Ding, YJ; Yan, L; He, DP; Wang, T; Chen, WM; Lu, Y; Lin, LW |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2004-08-01 |
| 卷号 | 25期号:8页码:653-658 |
| 关键词 | olefin hexene hydroformylation rhodium supported catalyst triphenyl phosphine organic-inorganic hybrid |
| 英文摘要 | the organic triphenyl-phosphine ligand was directly used to modify the rh/sio2 catalyst to prepare pph3-rh/sio2 catalyst for hydroformylation of olefins. the results showed that its catalytic activity for hydroformylation of 1-hexene under the mild conditions of 1.0 mpa and 373 k was higher than that of rh/sio2 catalyst, and comparable to that of the corresponding homogeneous hrhco(pph3)(3) catalyst. the pph3-rh/sio2 catalyst possessed the advantages of both heterogeneous catalysis and homogeneous catalysis, such as high activity, high selectivity and easy separation. by means of p-31 mas nmr and xps techniques for characterization of pph3-rh/sio2 catalyst, it was found that the coordination bond between rh metal and pph3 with lone-pair electron was formed on the catalyst. the pph3-rh/sio2 catalyst could be used in hydroformylation of olefins from c-2(=) to c-12(=). |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | phase-transfer ligands ; substituted triphenylphosphines ; 2-phase hydroformylation ; homogeneous catalysis ; hydrogenation ; rhodium ; metal ; complexes ; water |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000223853700013 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139549]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Nat Gas Utilizat & Appl Catalysis Lab, Liaoning 116023, Peoples R China 2.Chinese Acad Sci, Dalian Chem Phys, State Key Lab Catalysis, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, HJ,Ding, YJ,Yan, L,et al. Study on organic-inorganic hybrid L-Rh/SiO2 catalysts for hydroformylation of olefins catalytic performance and characterization of PPh3-Rh/SiO2 catalyst[J]. chinese journal of catalysis,2004,25(8):653-658. |
| APA | Zhu, HJ.,Ding, YJ.,Yan, L.,He, DP.,Wang, T.,...&Lin, LW.(2004).Study on organic-inorganic hybrid L-Rh/SiO2 catalysts for hydroformylation of olefins catalytic performance and characterization of PPh3-Rh/SiO2 catalyst.chinese journal of catalysis,25(8),653-658. |
| MLA | Zhu, HJ,et al."Study on organic-inorganic hybrid L-Rh/SiO2 catalysts for hydroformylation of olefins catalytic performance and characterization of PPh3-Rh/SiO2 catalyst".chinese journal of catalysis 25.8(2004):653-658. |
入库方式： OAI收割
来源：大连化学物理研究所
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