中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells

文献类型:期刊论文

作者Zhou, WJ; Li, WZ; Song, SQ; Zhou, ZH; Jiang, LH; Sun, GQ; Xin, Q; Poulianitis, K; Kontou, S; Tsiakaras, P
刊名journal of power sources
出版日期2004-05-14
卷号131期号:1-2页码:217-223
关键词direct ethanol fuel cells bi-metallic and tri-metallic catalysts ethanol energy
英文摘要in the present work, several pt-based anode catalysts supported on activated carbon xc-72r were prepared by using a novel method, characterized and tested. xrd analysis and tem images indicated that all of anode catalysts consist of uniform nanosized particles with sharp distribution and that the pt lattice parameter becomes shorter with the addition of ru and pd and bigger with the addition of sn and w. cyclic voltammetry (cv) measurements and single direct ethanol fuel cell (defc) tests jointly showed that sn, ru and w can enhance ethanol electro-oxidation activity of pt in the following order: pt1sn1/c > pt1ru1/c > pt1w1/c > pt1pd1 > pt/c. the pt1ru1/c catalyst was modified with mo, w and sn, respectively. it was found that the defcs performances were improved with these modified pt1ru1/c catalysts as anode catalysts. this distinct defc performance behavior is attributed to the so-called bifunctional mechanism and to the electronic interaction between pt and additives. (c) 2004 elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]electrochemistry ; energy & fuels
研究领域[WOS]electrochemistry ; energy & fuels
关键词[WOS]methanol electrooxidation ; platinum ; sn ; performance ; oxidation ; surface ; alloys ; ru
收录类别ISTP ; SCI
语种英语
WOS记录号WOS:000221418800032
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/139566]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Thessaloniki, Dept Mech & Ind Engn, Volos 38334, Greece
推荐引用方式
GB/T 7714
Zhou, WJ,Li, WZ,Song, SQ,et al. Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells[J]. journal of power sources,2004,131(1-2):217-223.
APA Zhou, WJ.,Li, WZ.,Song, SQ.,Zhou, ZH.,Jiang, LH.,...&Tsiakaras, P.(2004).Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells.journal of power sources,131(1-2),217-223.
MLA Zhou, WJ,et al."Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells".journal of power sources 131.1-2(2004):217-223.

入库方式: OAI收割

来源:大连化学物理研究所

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