Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells
文献类型:期刊论文
作者 | Zhou, WJ; Li, WZ; Song, SQ; Zhou, ZH; Jiang, LH; Sun, GQ; Xin, Q; Poulianitis, K; Kontou, S; Tsiakaras, P |
刊名 | journal of power sources
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出版日期 | 2004-05-14 |
卷号 | 131期号:1-2页码:217-223 |
关键词 | direct ethanol fuel cells bi-metallic and tri-metallic catalysts ethanol energy |
英文摘要 | in the present work, several pt-based anode catalysts supported on activated carbon xc-72r were prepared by using a novel method, characterized and tested. xrd analysis and tem images indicated that all of anode catalysts consist of uniform nanosized particles with sharp distribution and that the pt lattice parameter becomes shorter with the addition of ru and pd and bigger with the addition of sn and w. cyclic voltammetry (cv) measurements and single direct ethanol fuel cell (defc) tests jointly showed that sn, ru and w can enhance ethanol electro-oxidation activity of pt in the following order: pt1sn1/c > pt1ru1/c > pt1w1/c > pt1pd1 > pt/c. the pt1ru1/c catalyst was modified with mo, w and sn, respectively. it was found that the defcs performances were improved with these modified pt1ru1/c catalysts as anode catalysts. this distinct defc performance behavior is attributed to the so-called bifunctional mechanism and to the electronic interaction between pt and additives. (c) 2004 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | electrochemistry ; energy & fuels |
研究领域[WOS] | electrochemistry ; energy & fuels |
关键词[WOS] | methanol electrooxidation ; platinum ; sn ; performance ; oxidation ; surface ; alloys ; ru |
收录类别 | ISTP ; SCI |
语种 | 英语 |
WOS记录号 | WOS:000221418800032 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/139566] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Thessaloniki, Dept Mech & Ind Engn, Volos 38334, Greece |
推荐引用方式 GB/T 7714 | Zhou, WJ,Li, WZ,Song, SQ,et al. Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells[J]. journal of power sources,2004,131(1-2):217-223. |
APA | Zhou, WJ.,Li, WZ.,Song, SQ.,Zhou, ZH.,Jiang, LH.,...&Tsiakaras, P.(2004).Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells.journal of power sources,131(1-2),217-223. |
MLA | Zhou, WJ,et al."Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells".journal of power sources 131.1-2(2004):217-223. |
入库方式: OAI收割
来源:大连化学物理研究所
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