中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Enantiomer separation of dimethyl dicarboxy alpha-biphenyl (DDB) and its analogues on a covalently bonded cellulose tris-(3,5-dimethylphenyl-carbamate) CSP

文献类型:期刊论文

作者Qin, F; Chen, XM; Liu, YQ; Kong, L; Zou, HF
刊名journal of separation science
出版日期2004-10-01
卷号27期号:14页码:1195-1201
关键词enantiomeric separation mobile phase modifiers bonded type of CSP dimethyl dicarboxy biphenyl liquid chromatography
英文摘要dimethyl dicarboxy a-biphenyl (ddb) and its analogues represent atropisomers which have been resolved on the covalently bonded cellulose tris-(3,5-dimethylphenylcarbamate) (cdmpc) csp. different kinds of alcohols, tetrahydrofuran (thf), and chloroform were employed as mobile phase modifiers (mpms), and their influence on the retention and separation of the enantiomers was investigated. ternary mobile phases (hexane/2-propanol/thf, hexane/2-propanol/chloroform) were employed to investigate the separation of the five enantiomers. the advantages of the broader choice of solvents offered by the covalently bonded cdmpc csp were discussed. the effect of structural variation of the enantiomers on their retention and separation was investigated.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, analytical
研究领域[WOS]chemistry
关键词[WOS]chiral stationary phases ; performance liquid-chromatography ; silica-gel ; resolution ; derivatives ; tris(3,5-dimethylphenylcarbamate) ; ellagitannin
收录类别SCI
语种英语
WOS记录号WOS:000224783400007
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/139592]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatog Res & Anal Ctr, Dalian 116011, Peoples R China
推荐引用方式
GB/T 7714
Qin, F,Chen, XM,Liu, YQ,et al. Enantiomer separation of dimethyl dicarboxy alpha-biphenyl (DDB) and its analogues on a covalently bonded cellulose tris-(3,5-dimethylphenyl-carbamate) CSP[J]. journal of separation science,2004,27(14):1195-1201.
APA Qin, F,Chen, XM,Liu, YQ,Kong, L,&Zou, HF.(2004).Enantiomer separation of dimethyl dicarboxy alpha-biphenyl (DDB) and its analogues on a covalently bonded cellulose tris-(3,5-dimethylphenyl-carbamate) CSP.journal of separation science,27(14),1195-1201.
MLA Qin, F,et al."Enantiomer separation of dimethyl dicarboxy alpha-biphenyl (DDB) and its analogues on a covalently bonded cellulose tris-(3,5-dimethylphenyl-carbamate) CSP".journal of separation science 27.14(2004):1195-1201.

入库方式: OAI收割

来源:大连化学物理研究所

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