Heteropoly blue as a reaction-controlled phase-transfer catalyst for the epoxidation of olefins
文献类型：期刊论文
| 作者 | Li, MQ; Jian, XG |
| 刊名 | bulletin of the chemical society of japan
 |
| 出版日期 | 2005-08-15 |
| 卷号 | 78期号:8页码:1575-1579 |
| 英文摘要 | a new reaction-controlled phase-transfer catalyst system has been designed and synthesized. in this system, heteropoly blue, [c7h7n(ch3)(3)](3)pmo4o16, is used for the catalytic epoxidation of olefins with h2o2 as the oxidant. in this system, the catalyst not only can be recovered, like heterogeneous catalyst, but also acts as a homogeneous catalyst. the main products are epoxide of olefins and h2o; no co-product forms. the system exhibits high conversion and selectivity as well as excellent catalyst stability. (pnmr)-p-31 spectra, uv-vis spectra, and infrared spectra are used to analyze the reason for the phase transfer of the catalyst, indicating that the change of structure leads to the formation of reaction-controlled phase-transfer catalyst. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | hydrogen-peroxide ; oxidation ; complexes ; alcohols ; alkenes ; systems ; oxide |
| 收录类别 | SCI ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000231523300026 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139627]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Dept Polymer Sci & Mat, Dalian 116012, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, MQ,Jian, XG. Heteropoly blue as a reaction-controlled phase-transfer catalyst for the epoxidation of olefins[J]. bulletin of the chemical society of japan,2005,78(8):1575-1579. |
| APA | Li, MQ,&Jian, XG.(2005).Heteropoly blue as a reaction-controlled phase-transfer catalyst for the epoxidation of olefins.bulletin of the chemical society of japan,78(8),1575-1579. |
| MLA | Li, MQ,et al."Heteropoly blue as a reaction-controlled phase-transfer catalyst for the epoxidation of olefins".bulletin of the chemical society of japan 78.8(2005):1575-1579. |
入库方式： OAI收割
来源：大连化学物理研究所
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