Pt catalyst supported on carbon nanotubes for selective hydrogenation of citral and differential heats of CO adsorption
文献类型:期刊论文
作者 | Zhang, YJ; Li, JY; Li, WZ; Xin, Q |
刊名 | chemical journal of chinese universities-chinese
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出版日期 | 2005-07-10 |
卷号 | 26期号:7页码:1345-1347 |
关键词 | selective hydrogenation of citral differential heats of CO adsorption Pt catalyst supported on carbon nanotubes |
英文摘要 | carbon nanotube is found to be a novel support for the selective hydrogenation of citral in this paper. selective hydrogenation of citral was carried out in an autoclave at 5 mpa and 323 k. the results indicate that the selectivity of the products, unsaturated alcohols, is about 86% over pt/cnts catalyst and 48% over pt/xc-72 catalyst, respectively. the differential heat of co adsorption measured by microcalorimetry is firstly used to probe surface adsorption sites of platinum catalyst supported on carbon nanotubes. the experimental results indicate that the pt/cnts catalyst shows a higher initial differential heat of co adsorption (126 kj/mol) than the pt/xc-72 catalyst(106 kj/mol). |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, multidisciplinary |
研究领域[WOS] | chemistry |
关键词[WOS] | platinum |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000230753000039 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/139676] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Xian Jiaotong Univ, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R China 2.Xian Petr Univ, Coll Chem & Chem Engn, Xian 710065, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catal Basis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, YJ,Li, JY,Li, WZ,et al. Pt catalyst supported on carbon nanotubes for selective hydrogenation of citral and differential heats of CO adsorption[J]. chemical journal of chinese universities-chinese,2005,26(7):1345-1347. |
APA | Zhang, YJ,Li, JY,Li, WZ,&Xin, Q.(2005).Pt catalyst supported on carbon nanotubes for selective hydrogenation of citral and differential heats of CO adsorption.chemical journal of chinese universities-chinese,26(7),1345-1347. |
MLA | Zhang, YJ,et al."Pt catalyst supported on carbon nanotubes for selective hydrogenation of citral and differential heats of CO adsorption".chemical journal of chinese universities-chinese 26.7(2005):1345-1347. |
入库方式: OAI收割
来源:大连化学物理研究所
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