Application of ferrocene-derived chiral S,P-donor ligands for iridium-catalyzed asymmetric hydrogenation of quinolines
文献类型：期刊论文
| 作者 | Zhao, YJ; Wang, YQ; Zhou, YG |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2005-09-01 |
| 卷号 | 26期号:9页码:737-739 |
| 关键词 | ferrocene chiral S iridium quinoline asymmetric hydrogenation P-donor ligand |
| 英文摘要 | chiral s,p-donor ferrocene-derived ligands were synthesized and applied in the asymmetric hydrogenation of quinolines using the [ir(cod)cl](2)/s, p-ligand complex as the catalyst in the presence of iodine. the effects of the solvent and hydrogen pressure on conversion and enantioselectivity were examined, and up to 82% ee was obtained. the planar chirality plays an important role in this reaction. r- and s-enantiomers of 1 2,3,4-tetrahydroquinoline derivatives were obtained using ligands 3 and 5, respectively. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | hydrosilylation ; backbone |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000232474800004 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139711]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, YJ,Wang, YQ,Zhou, YG. Application of ferrocene-derived chiral S,P-donor ligands for iridium-catalyzed asymmetric hydrogenation of quinolines[J]. chinese journal of catalysis,2005,26(9):737-739. |
| APA | Zhao, YJ,Wang, YQ,&Zhou, YG.(2005).Application of ferrocene-derived chiral S,P-donor ligands for iridium-catalyzed asymmetric hydrogenation of quinolines.chinese journal of catalysis,26(9),737-739. |
| MLA | Zhao, YJ,et al."Application of ferrocene-derived chiral S,P-donor ligands for iridium-catalyzed asymmetric hydrogenation of quinolines".chinese journal of catalysis 26.9(2005):737-739. |
入库方式： OAI收割
来源：大连化学物理研究所
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