Direct ethanol fuel cells based on PtSn anodes: the effect of Sn content on the fuel cell performance
文献类型：期刊论文
| 作者 | Zhou, WJ; Song, SQ; Li, WZ; Zhou, ZH; Sun, GQ; Xin, Q; Douvartzides, S; Tsiakaras, P |
| 刊名 | journal of power sources
 |
| 出版日期 | 2005-01-10 |
| 卷号 | 140期号:1页码:50-58 |
| 关键词 | direct ethanol fuel cells PtSn/C anode catalysts |
| 英文摘要 | in the present work, several carbon supported ptsn catalysts with different pt/sn atomic ratios were synthesized and characterized by x-ray diffraction (xrd), transmission electron microscopy (tem) and x-ray photoelectron spectroscopy (xps). both the results of tem and xrd showed that all in-house prepared carbon supported pt and ptsn catalysts had nanosized particles with narrow size distribution. according to the primary analysis of xps results, it was confirmed that the main part of pt of the as-prepared catalysts is in metallic state while the main part of sn is in oxidized state. the performances of single direct ethanol fuel cells were different from each other with different anode catalysts and at different temperatures. it was found that, the single defc employing pt3sn2/c showed better performance at 60degreesc while the direct ethanol fuel cells with pt2sn1/c and pt3sn2/c exhibited similar performances at 75 degreesc. furthermore, at 90 degreesc, pt2sn1/c was identified as a more suitable anode catalyst for direct ethanol fuel cells in terms of the fuel cell maximum power density. surface oxygen-containing species, lattice parameters and ohmic effects, which are related to the sn content, are thought as the main factors influencing the catalyst activity and consequently the performance of single direct ethanol fuel cells. (c) 2004 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | electrochemistry ; energy & fuels |
| 研究领域[WOS] | electrochemistry ; energy & fuels |
| 关键词[WOS] | methanol electrooxidation ; ru ; electrocatalysts ; oxidation ; catalysts ; platinum ; tin ; electrodes ; progress ; stack |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000226265900007 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139726]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Inst Chem Phys, Direct Alcohol Fuel Cell Lab, CAS, Dalian 116023, Peoples R China 2.Dalian Inst Chem Phys, State Key Lab Catalysis, CAS, Dalian 116023, Peoples R China 3.Univ Thessaloniki, Sch Engn, Dept Mech & Ind Engn, Volos 38334, Greece |
| 推荐引用方式 GB/T 7714 | Zhou, WJ,Song, SQ,Li, WZ,et al. Direct ethanol fuel cells based on PtSn anodes: the effect of Sn content on the fuel cell performance[J]. journal of power sources,2005,140(1):50-58. |
| APA | Zhou, WJ.,Song, SQ.,Li, WZ.,Zhou, ZH.,Sun, GQ.,...&Tsiakaras, P.(2005).Direct ethanol fuel cells based on PtSn anodes: the effect of Sn content on the fuel cell performance.journal of power sources,140(1),50-58. |
| MLA | Zhou, WJ,et al."Direct ethanol fuel cells based on PtSn anodes: the effect of Sn content on the fuel cell performance".journal of power sources 140.1(2005):50-58. |
入库方式： OAI收割
来源：大连化学物理研究所
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