Measurement of low-temperature heat capacity and standard enthalpy of formation of praseodymium glycin perchlorate complex
文献类型：期刊论文
| 作者 | Wu, XM; Song, YJ; Tan, ZC; Qu, SS |
| 刊名 | chinese journal of chemical physics
 |
| 出版日期 | 2005-04-01 |
| 卷号 | 18期号:2页码:284-288 |
| 关键词 | rare earth salt DL-alpha-Glycin [Pr-2(DL-alpha-Gly)(6)(H2O)(4)](ClO4)6 center dot 5H2O low-temperature heat capacity standard enthalpy of formation |
| 英文摘要 | the rare-earth perchlorate complex compound with dl-α-glycin was synthesized. its structure was characterized as [pr-2 (dl-α-gly)(6)(h2o)(4)] (clo4)(6) • 5h(2)o by tg, dta and chemical analysis, and the purity was 99.63%. the melting point analysis experiment indicates that the complex has no stable melting point. the heat capacity of the complex was measured by a high-precise fully-automated adiabatic calorimeter from 79 to 371 k. no obvious abnormal heat capacity was observed within this low temperature range. the thermal decomposition temperature range of the complex was near 333 k. its decomposition temperature, decomposition enthalpy and entropy were 320.010 k, 40.714 kj/mol and 127.227 j/molk, respectively. the polynomial equation of heat capacity of this compound was simulated by the computer within the temperature range of 78.939 ∼ 301.295 k. the standard enthalpy of formation was -8022.802 kj/mol measured by isoperable reaction calorimeter at 298.15 k. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000228910100026 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139784]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Beijing Inst Petrochem Technol, Dept Chem Engn, Beijing 102617, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China 3.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, XM,Song, YJ,Tan, ZC,et al. Measurement of low-temperature heat capacity and standard enthalpy of formation of praseodymium glycin perchlorate complex[J]. chinese journal of chemical physics,2005,18(2):284-288. |
| APA | Wu, XM,Song, YJ,Tan, ZC,&Qu, SS.(2005).Measurement of low-temperature heat capacity and standard enthalpy of formation of praseodymium glycin perchlorate complex.chinese journal of chemical physics,18(2),284-288. |
| MLA | Wu, XM,et al."Measurement of low-temperature heat capacity and standard enthalpy of formation of praseodymium glycin perchlorate complex".chinese journal of chemical physics 18.2(2005):284-288. |
入库方式： OAI收割
来源：大连化学物理研究所
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