Selenium-catalyzed reduction of m-dinitrobenzene to m-nitroaniline by carbon monoxide and water
文献类型：期刊论文
| 作者 | Liu, XZ; Lu, SW |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2005 |
| 卷号 | 26期号:1页码:74-78 |
| 关键词 | selenium reduction m-dinitrobenzene m-nitroaniline carbon monoxide water |
| 英文摘要 | applying co/h2o reaction as a hydrogen source for the reduction of aromatic nitro compounds to corresponding amines is of great potential from a technological point of view, especially when a cheap catalytic system can be employed. selenium- catalyzed reduction of m-dinitrobenzene (dnb) to m-nitroaniline (nal) by co/h2o with naoac as a co-catalyst was studied. the effects of time, carbon monoxide pressure, temperature, selenium/nitrobenzene mole ratio, solvent amount and water amount on the dnb conversion i nal selectivity and nal yield were investigated. when the reaction proceeded at theta= 160 degreesc and p (co) =1 mpa for 3 h, using thf as a solvent, with n (h2o) /n (dnb) = 20 and n (se) /n (dnb) = 0. 04, the dnb conversion was up to 100% with nal selectivity and nal yield of 95.7%. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | aromatic nitro-compounds ; amines |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000227023300016 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139865]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116023, Peoples R China 2.Liaoning Univ, Inst Rare & Scattered Met Chem, Shenyang 110036, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, XZ,Lu, SW. Selenium-catalyzed reduction of m-dinitrobenzene to m-nitroaniline by carbon monoxide and water[J]. chinese journal of catalysis,2005,26(1):74-78. |
| APA | Liu, XZ,&Lu, SW.(2005).Selenium-catalyzed reduction of m-dinitrobenzene to m-nitroaniline by carbon monoxide and water.chinese journal of catalysis,26(1),74-78. |
| MLA | Liu, XZ,et al."Selenium-catalyzed reduction of m-dinitrobenzene to m-nitroaniline by carbon monoxide and water".chinese journal of catalysis 26.1(2005):74-78. |
入库方式： OAI收割
来源：大连化学物理研究所
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