Direct ethanol PEM fuel cells: The case of platinum based anodes
文献类型：期刊论文
| 作者 | Song, SQ; Zhou, WJ; Zhou, ZH; Jiang, LH; Sun, GQ; Xin, Q; Leontidis, V; Kontou, S; Tsiakaras, P |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2005-08-01 |
| 卷号 | 30期号:9页码:995-1001 |
| 关键词 | direct ethanol fuel cells PtSn/C PtRu/C ethanol electrooxidation |
| 英文摘要 | ptsn/c catalysts were prepared by the direct decoration of pt/c with sn through a modified poly process. xrd results showed there existed obvious sno2 in this catalyst, different from the ptsn/c prepared by co-precipitation, sn presenting in different valence. the techniques of cyclic voltammetry, anode polarization curve and single direct ethanol fuel cell (defc) tests were used to evaluate and compare the electrocatalytic activities to ethanol oxidation over ptsn/c prepared by different preparation procedure and over the commercial ptru/c catalyst. the experimental results showed that ptsn/c presents higher electrocatalytic activity than ptru/c. the results also showed that, compared to the ptsn/c prepared by co-precipitation, ptsn/c in this investigation exhibits a similar initial activity but a lower activity along with the current density increment, probably due to its poor electronic conductivity and part coverage of platinum active sites resulting from sno2. it was found from the gc analysis results that ptsn/c can oxidize ethanol molecules to a deeper extent than ptru/c, leading to both a higher fuel utilization coefficient and a higher fuel cell efficiency. (c) 2005 international association for hydrogen energy. published by elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
| 研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
| 关键词[WOS] | pt-ru ; methanol oxidation ; mass-spectrometry ; electrodes ; electrooxidation ; catalysts ; enhancement ; performance ; carbon ; area |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000229710200008 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139882]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.CAS, Dalian Inst Chem Phys, Direct Alcohol Fuel Cell Lab, Dalian 116023, Peoples R China 2.CAS, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Thessaly, Sch Engn, Dept Mech Engn, Thessaly 38334, Greece |
| 推荐引用方式 GB/T 7714 | Song, SQ,Zhou, WJ,Zhou, ZH,et al. Direct ethanol PEM fuel cells: The case of platinum based anodes[J]. international journal of hydrogen energy,2005,30(9):995-1001. |
| APA | Song, SQ.,Zhou, WJ.,Zhou, ZH.,Jiang, LH.,Sun, GQ.,...&Tsiakaras, P.(2005).Direct ethanol PEM fuel cells: The case of platinum based anodes.international journal of hydrogen energy,30(9),995-1001. |
| MLA | Song, SQ,et al."Direct ethanol PEM fuel cells: The case of platinum based anodes".international journal of hydrogen energy 30.9(2005):995-1001. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。