Direct methanol fuel cells: The influence of methanol on the reduction of oxygen over Pt/C catalysts with different particle sizes
文献类型:期刊论文
作者 | Li, WZ; Song, SQ; Zhou, WJ; Sun, GQ; Xin, Q; Poulianitis, C; Tsiakaras, P |
刊名 | ionics
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出版日期 | 2005 |
卷号 | 11期号:1-2页码:112-119 |
英文摘要 | two pt/c catalysts with different particle sizes (pt/c: 2.5 run, pt/c-700ar: 5.1 nm) were investigated by applying a half-cell configuration - rotating disk electrode (rde) technique in h2so4, aqueous solutions in the absence of or in the presence of methanol with different concentrations. pt/c catalyst exhibited higher mass activity in h2so, aqueous solution without methanol and slightly lower mass activity in h2so4 plus 0.1 mol/l ch3oh in comparison with that of pt/c-700ar catalyst. on the contrary, single direct methanol fuel cell (dmfc) tests showed that pt/c exhibited higher oxygen, reduction reaction (orr) activity and better cell performance, mainly due to the different kinds of electrolyte properties. furthermore, it suggested that a better single dmfc performance could be obtained with a smaller particle size pt-based cathode catalyst. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical ; electrochemistry ; physics, condensed matter |
研究领域[WOS] | chemistry ; electrochemistry ; physics |
关键词[WOS] | transition-metal sulfides ; carbon-supported platinum ; cathode catalyst ; disk electrode ; nanotubes ; electrocatalysts ; electroreduction ; membranes |
收录类别 | ISTP ; SCI |
语种 | 英语 |
WOS记录号 | WOS:000228650400014 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/139898] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Direct Alcohol Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Thessaloniki, Sch Engn, Dept Mech & Ind Engn, Volos, Greece |
推荐引用方式 GB/T 7714 | Li, WZ,Song, SQ,Zhou, WJ,et al. Direct methanol fuel cells: The influence of methanol on the reduction of oxygen over Pt/C catalysts with different particle sizes[J]. ionics,2005,11(1-2):112-119. |
APA | Li, WZ.,Song, SQ.,Zhou, WJ.,Sun, GQ.,Xin, Q.,...&Tsiakaras, P.(2005).Direct methanol fuel cells: The influence of methanol on the reduction of oxygen over Pt/C catalysts with different particle sizes.ionics,11(1-2),112-119. |
MLA | Li, WZ,et al."Direct methanol fuel cells: The influence of methanol on the reduction of oxygen over Pt/C catalysts with different particle sizes".ionics 11.1-2(2005):112-119. |
入库方式: OAI收割
来源:大连化学物理研究所
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