Furrocene-based chiral phosphine-triazines: A new family of highly efficient P,N ligands for asymmetric catalysis
文献类型：期刊论文
| 作者 | Hu, XP; Chen, HL; Zheng, Z |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2005-03-01 |
| 卷号 | 347期号:4页码:541-548 |
| 关键词 | allylic alkylation asymmetric catalysis palladium phosphine-triazine ligands P N ligands |
| 英文摘要 | the presence of the additional heterocyclic nitrogen atoms in chiral pn ligands has an important influence on the asymmetric catalysis, and a clear trend was observed in the present research that the enantioselectivity and reactivity were significantly increased by raising the number of heterocyclic nitrogen atoms in these pn ligands. through finely tuning the number of heterocyclic nitrogen atoms, a new family of ferrocene-based chiral phosphine-triazine ligands with three heterocyclic nitrogen atoms has been developed and successfully applied in pd-catalyzed asymmetric allylic substitution. up to 99% ee with 99% yield of allylic alkylation products and 94% ee of allylic amination products have been obtained by the use of ligand (r-c,s-p)-1f with a 4,6-diphenoxy-1,3,5-triazine moiety. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | ferrocenylphosphine-amidine ligands ; allylic alkylation ; ferrocene ligands ; practical ligands ; metal-complexes ; imine ligands ; hydroboration ; substitutions ; p,n-ligands ; resolution |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000227764500008 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139925]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, XP,Chen, HL,Zheng, Z. Furrocene-based chiral phosphine-triazines: A new family of highly efficient P,N ligands for asymmetric catalysis[J]. advanced synthesis & catalysis,2005,347(4):541-548. |
| APA | Hu, XP,Chen, HL,&Zheng, Z.(2005).Furrocene-based chiral phosphine-triazines: A new family of highly efficient P,N ligands for asymmetric catalysis.advanced synthesis & catalysis,347(4),541-548. |
| MLA | Hu, XP,et al."Furrocene-based chiral phosphine-triazines: A new family of highly efficient P,N ligands for asymmetric catalysis".advanced synthesis & catalysis 347.4(2005):541-548. |
入库方式： OAI收割
来源：大连化学物理研究所
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