Reversal of stereochemistry by adding Ti((OPr)-Pr-i)(4) in the enantioselective phenylacetylene addition to aldehydes using L-prolinol-backbone ligand
文献类型：期刊论文
| 作者 | Mao, JC; Wan, BS; Wu, F; Wang, RL; Lu, SW |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 2005-05-03 |
| 卷号 | 232期号:1-2页码:9-12 |
| 关键词 | reversal of stereochemistry enantioselective alkynylzinc addition L-prolinol-backbone propargylic alcohol aldehyde |
| 英文摘要 | chiral ligands 1-2 with l-prolinol backbone have been applied to the enantioselective phenylacetylene addition to aldehydes, providing chiral propargylic alcohols in high yields and moderate enantioselectivities. only the ligand 1 in combination with ti((opr)-pr-i)(4) afforded the products with opposite absolute configuration in significant enantiomeric excesses and high yields. the ratio of ti((opr)-pr-i)(4) to the ligand had great influence on the enantiomeric excess of the product. (c) 2005 elsevier b.v. all fights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | asymmetric addition ; aromatic-aldehydes ; diethylzinc ; alcohols ; alkynylation ; alkynylzinc ; catalysts ; titanium ; complex ; ketones |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000228203100002 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/139929]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mao, JC,Wan, BS,Wu, F,et al. Reversal of stereochemistry by adding Ti((OPr)-Pr-i)(4) in the enantioselective phenylacetylene addition to aldehydes using L-prolinol-backbone ligand[J]. journal of molecular catalysis a-chemical,2005,232(1-2):9-12. |
| APA | Mao, JC,Wan, BS,Wu, F,Wang, RL,&Lu, SW.(2005).Reversal of stereochemistry by adding Ti((OPr)-Pr-i)(4) in the enantioselective phenylacetylene addition to aldehydes using L-prolinol-backbone ligand.journal of molecular catalysis a-chemical,232(1-2),9-12. |
| MLA | Mao, JC,et al."Reversal of stereochemistry by adding Ti((OPr)-Pr-i)(4) in the enantioselective phenylacetylene addition to aldehydes using L-prolinol-backbone ligand".journal of molecular catalysis a-chemical 232.1-2(2005):9-12. |
入库方式： OAI收割
来源：大连化学物理研究所
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