Thermochemistry of Zn(AA)SO4 center dot H2O(s) (AA = L-alpha-valine and methionine)
文献类型:期刊论文
作者 | Di, YY; Tan, ZC; Gao, SL; Sun, LX |
刊名 | thermochimica acta
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出版日期 | 2005-10-01 |
卷号 | 436期号:1-2页码:150-152 |
关键词 | isoperibol temperature-rise calorimetry valine and methionine complexs of Zn(II) molar enthalpy of dissolution molar enthalpy of formation |
英文摘要 | the standard molar enthalpies of dissolution of {znso(4)(.)7h(2)o(s)+val(s)}, {znso(4)(.)7h(2)o(s)+met(s)}, zn(val)(so4h2o)-h-.(s) and zn(met)so4-h2o(s) (where val is l-alpha-valine and met is l-alpha-methionine) in 2 mol dm(-3) hcl at t = 298.15 +/- 0.001 k have been measured to be delta(d)h(m,l)degrees = 94.588 +/- 0.025 kj mol(-1), delta(d)h(m,3)degrees = -46.118 +/- 0.055 kj mol(-1), delta(d)h(m,4)degrees = -70.619 +/- 0.051 kj mol(-1), delta(d)h(m,5)degrees = 58.415 +/- 0.046 kj mol(-1), respectively. the derived molar enthalpies of formation of the complexes zn(val)(so4h2o)-h-.(s) and zn(met)(so4h2o)-h-.(s) are delta(f)h(m)degrees[zn(val)(so4h2o)-h-., s] = -1851 +/- 2 kj mol(-1) and delta(f)h(m)degrees[zn(met)so4 (.) h2o, s] = -2069 +/- 0.7 j mol(-1). (c) 2005 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, analytical ; chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | standard molar enthalpy ; calorimeter |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000232179700022 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/139932] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China 3.NW Univ Xian, Dept Chem, Xian 710069, Peoples R China |
推荐引用方式 GB/T 7714 | Di, YY,Tan, ZC,Gao, SL,et al. Thermochemistry of Zn(AA)SO4 center dot H2O(s) (AA = L-alpha-valine and methionine)[J]. thermochimica acta,2005,436(1-2):150-152. |
APA | Di, YY,Tan, ZC,Gao, SL,&Sun, LX.(2005).Thermochemistry of Zn(AA)SO4 center dot H2O(s) (AA = L-alpha-valine and methionine).thermochimica acta,436(1-2),150-152. |
MLA | Di, YY,et al."Thermochemistry of Zn(AA)SO4 center dot H2O(s) (AA = L-alpha-valine and methionine)".thermochimica acta 436.1-2(2005):150-152. |
入库方式: OAI收割
来源:大连化学物理研究所
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